| 1 | Sat 13 Aug 2022 | 263-0 v Real ValladolidReal Valladolid 0-3 Villarreal | Spanish La Liga |
| 2 | Thu 18 Aug 2022 | 264-2 v Hajduk SplitVillarreal 4-2 Hajduk Split | UEFA Europa Conference League Play-off |
| 3 | Sun 21 Aug 2022 | 262-0 v Atlético MadridAtlético Madrid 0-2 Villarreal | Spanish La Liga |
| 4 | Thu 25 Aug 2022 | 262-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 5 | Sun 28 Aug 2022 | 150-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 6 | Sun 4 Sep 2022 | 15 4-0 v ElcheVillarreal 4-0 Elche | Spanish La Liga |
| 7 | Thu 8 Sep 2022 | 154-3 v Lech PoznańVillarreal 4-3 Lech Poznań | UEFA Europa Conference League Group C |
| 8 | Sun 11 Sep 2022 | 150-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 9 | Thu 15 Sep 2022 | 152-1 v Hapoel Be-er ShevaHapoel Be-er Sheva 1-2 Villarreal | UEFA Europa Conference League Group C |
| 10 | Sun 18 Sep 2022 | 151-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 11 | Sat 1 Oct 2022 | 150-0 v CádizCádiz 0-0 Villarreal | Spanish La Liga |
| 12 | Thu 6 Oct 2022 | 155-0 v Austria ViennaVillarreal 5-0 Austria Vienna | UEFA Europa Conference League Group C |
| 13 | Sun 9 Oct 2022 | 150-1 v Real SociedadReal Sociedad 1-0 Villarreal | Spanish La Liga |
| 14 | Thu 13 Oct 2022 | 15 1-0 v Austria ViennaAustria Vienna 0-1 Villarreal | UEFA Europa Conference League Group C |
| 15 | Mon 17 Oct 2022 | 152-0 v OsasunaVillarreal 2-0 Osasuna | Spanish La Liga |
| 16 | Thu 20 Oct 2022 | 150-3 v BarcelonaBarcelona 3-0 Villarreal | Spanish La Liga |
| 17 | Sun 23 Oct 2022 | 152-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 18 | Thu 27 Oct 2022 | 152-2 v Hapoel Be-er ShevaVillarreal 2-2 Hapoel Be-er Sheva | UEFA Europa Conference League Group C |
| 19 | Sun 30 Oct 2022 | 150-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 20 | Thu 3 Nov 2022 | 150-3 v Lech PoznańLech Poznań 3-0 Villarreal | UEFA Europa Conference League Group C |
| 21 | Sun 6 Nov 2022 | 150-2 v MallorcaVillarreal 0-2 Mallorca | Spanish La Liga |
| 22 | Sat 31 Dec 2022 | 152-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 23 | Thu 9 Mar 2023 | 151-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 24 | Sun 12 Mar 2023 | 151-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 25 | Thu 16 Mar 2023 | 150-1 v RSC AnderlechtVillarreal 0-1 RSC Anderlecht | UEFA Europa Conference League Round of 16 |
| 26 | Sun 2 Apr 2023 | 15 2-0 v Real SociedadVillarreal 2-0 Real Sociedad | Spanish La Liga |
| 27 | Sat 15 Apr 2023 | 151-2 v Real ValladolidVillarreal 1-2 Real Valladolid | Spanish La Liga |
| 28 | Sun 23 Apr 2023 | 151-2 v SevillaSevilla 2-1 Villarreal | Spanish La Liga |
| 29 | Thu 27 Apr 2023 | 15 4-2 v EspanyolVillarreal 4-2 Espanyol | Spanish La Liga |
| 30 | Sun 30 Apr 2023 | 153-1 v Celta VigoVillarreal 3-1 Celta Vigo | Spanish La Liga |
| 31 | Wed 3 May 2023 | 15 1-1 v ValenciaValencia 1-1 Villarreal | Spanish La Liga |
| 32 | Sat 13 May 2023 | 155-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 33 | Sat 20 May 2023 | 152-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 34 | Wed 24 May 2023 | 152-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 35 | Sun 28 May 2023 | 15 1-2 v Rayo VallecanoRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 36 | Sun 4 Jun 2023 | 152-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
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