| 1 | Sat 13 Aug 2022 | 83-0 v Real ValladolidReal Valladolid 0-3 Villarreal | Spanish La Liga |
| 2 | Sun 21 Aug 2022 | 82-0 v Atlético MadridAtlético Madrid 0-2 Villarreal | Spanish La Liga |
| 3 | Thu 25 Aug 2022 | 82-0 v Hajduk SplitHajduk Split 0-2 Villarreal | UEFA Europa Conference League Play-off |
| 4 | Sun 28 Aug 2022 | 80-0 v GetafeGetafe 0-0 Villarreal | Spanish La Liga |
| 5 | Wed 9 Nov 2022 | 81-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 6 | Sat 31 Dec 2022 | 8 2-1 v ValenciaVillarreal 2-1 Valencia | Spanish La Liga |
| 7 | Sat 7 Jan 2023 | 82-1 v Real MadridVillarreal 2-1 Real Madrid | Spanish La Liga |
| 8 | Fri 13 Jan 2023 | 81-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 9 | Mon 30 Jan 2023 | 8 0-1 v Rayo VallecanoVillarreal 0-1 Rayo Vallecano | Spanish La Liga |
| 10 | Sat 4 Feb 2023 | 81-3 v ElcheElche 3-1 Villarreal | Spanish La Liga |
| 11 | Sun 12 Feb 2023 | 80-1 v BarcelonaVillarreal 0-1 Barcelona | Spanish La Liga |
| 12 | Sat 18 Feb 2023 | 82-4 v MallorcaMallorca 4-2 Villarreal | Spanish La Liga |
| 13 | Mon 27 Feb 2023 | 82-1 v GetafeVillarreal 2-1 Getafe | Spanish La Liga |
| 14 | Sat 4 Mar 2023 | 8 2-0 v AlmeríaAlmería 0-2 Villarreal | Spanish La Liga |
| 15 | Thu 9 Mar 2023 | 81-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 16 | Sun 12 Mar 2023 | 81-1 v Real BetisVillarreal 1-1 Real Betis | Spanish La Liga |
| 17 | Thu 16 Mar 2023 | 80-1 v RSC AnderlechtVillarreal 0-1 RSC Anderlecht | UEFA Europa Conference League Round of 16 |
| 18 | Sun 19 Mar 2023 | 83-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 19 | Sun 2 Apr 2023 | 8 2-0 v Real SociedadVillarreal 2-0 Real Sociedad | Spanish La Liga |
| 20 | Sat 8 Apr 2023 | 8 3-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 21 | Sun 23 Apr 2023 | 8 1-2 v SevillaSevilla 2-1 Villarreal | Spanish La Liga |
| 22 | Thu 27 Apr 2023 | 84-2 v EspanyolVillarreal 4-2 Espanyol | Spanish La Liga |
| 23 | Sun 30 Apr 2023 | 83-1 v Celta VigoVillarreal 3-1 Celta Vigo | Spanish La Liga |
| 24 | Wed 3 May 2023 | 81-1 v ValenciaValencia 1-1 Villarreal | Spanish La Liga |
| 25 | Sat 13 May 2023 | 85-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 26 | Sat 20 May 2023 | 82-1 v GironaGirona 1-2 Villarreal | Spanish La Liga |
| 27 | Sun 28 May 2023 | 81-2 v Rayo VallecanoRayo Vallecano 2-1 Villarreal | Spanish La Liga |
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