| 1 | Thu 8 Sep 2022 | 124-3 v Lech PoznańVillarreal 4-3 Lech Poznań | UEFA Europa Conference League Group C |
| 2 | Sun 11 Sep 2022 | 120-1 v Real BetisReal Betis 1-0 Villarreal | Spanish La Liga |
| 3 | Thu 15 Sep 2022 | 12 2-1 v Hapoel Be-er ShevaHapoel Be-er Sheva 1-2 Villarreal | UEFA Europa Conference League Group C |
| 4 | Sun 18 Sep 2022 | 121-1 v SevillaVillarreal 1-1 Sevilla | Spanish La Liga |
| 5 | Thu 6 Oct 2022 | 125-0 v Austria ViennaVillarreal 5-0 Austria Vienna | UEFA Europa Conference League Group C |
| 6 | Thu 13 Oct 2022 | 121-0 v Austria ViennaAustria Vienna 0-1 Villarreal | UEFA Europa Conference League Group C |
| 7 | Thu 20 Oct 2022 | 120-3 v BarcelonaBarcelona 3-0 Villarreal | Spanish La Liga |
| 8 | Sun 23 Oct 2022 | 122-1 v AlmeríaVillarreal 2-1 Almería | Spanish La Liga |
| 9 | Thu 27 Oct 2022 | 122-2 v Hapoel Be-er ShevaVillarreal 2-2 Hapoel Be-er Sheva | UEFA Europa Conference League Group C |
| 10 | Thu 3 Nov 2022 | 120-3 v Lech PoznańLech Poznań 3-0 Villarreal | UEFA Europa Conference League Group C |
| 11 | Sun 6 Nov 2022 | 120-2 v MallorcaVillarreal 0-2 Mallorca | Spanish La Liga |
| 12 | Fri 13 Jan 2023 | 121-1 v Celta VigoCelta Vigo 1-1 Villarreal | Spanish La Liga |
| 13 | Sun 22 Jan 2023 | 121-0 v GironaVillarreal 1-0 Girona | Spanish La Liga |
| 14 | Mon 30 Jan 2023 | 120-1 v Rayo VallecanoVillarreal 0-1 Rayo Vallecano | Spanish La Liga |
| 15 | Sat 4 Feb 2023 | 121-3 v ElcheElche 3-1 Villarreal | Spanish La Liga |
| 16 | Sun 12 Feb 2023 | 120-1 v BarcelonaVillarreal 0-1 Barcelona | Spanish La Liga |
| 17 | Sat 18 Feb 2023 | 122-4 v MallorcaMallorca 4-2 Villarreal | Spanish La Liga |
| 18 | Mon 27 Feb 2023 | 122-1 v GetafeVillarreal 2-1 Getafe | Spanish La Liga |
| 19 | Sat 4 Mar 2023 | 122-0 v AlmeríaAlmería 0-2 Villarreal | Spanish La Liga |
| 20 | Thu 9 Mar 2023 | 121-1 v RSC AnderlechtRSC Anderlecht 1-1 Villarreal | UEFA Europa Conference League Round of 16 |
| 21 | Sun 19 Mar 2023 | 123-0 v OsasunaOsasuna 0-3 Villarreal | Spanish La Liga |
| 22 | Sat 8 Apr 2023 | 123-2 v Real MadridReal Madrid 2-3 Villarreal | Spanish La Liga |
| 23 | Sat 13 May 2023 | 125-1 v Athletic BilbaoVillarreal 5-1 Athletic Bilbao | Spanish La Liga |
| 24 | Wed 24 May 2023 | 122-0 v CádizVillarreal 2-0 Cádiz | Spanish La Liga |
| 25 | Sun 4 Jun 2023 | 122-2 v Atlético MadridVillarreal 2-2 Atlético Madrid | Spanish La Liga |
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