| 1 | Sun 1 Sep 2019 | 2-2 v Real MadridVillarreal 2-2 Real Madrid | Spanish La Liga |
| 2 | Sat 14 Sep 2019 | 3-0 v LeganésLeganés 0-3 Villarreal | Spanish La Liga |
| 3 | Sat 21 Sep 2019 | 2-0 v Real ValladolidVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 4 | Tue 24 Sep 2019 | 1-2 v BarcelonaBarcelona 2-1 Villarreal | Spanish La Liga |
| 5 | Fri 27 Sep 2019 | 5-1 v Real BetisVillarreal 5-1 Real Betis | Spanish La Liga |
| 6 | Sat 5 Oct 2019 | 1-2 v OsasunaOsasuna 2-1 Villarreal | Spanish La Liga |
| 7 | Sun 20 Oct 2019 | 1-0 v EspanyolEspanyol 0-1 Villarreal | Spanish La Liga |
| 8 | Fri 25 Oct 2019 | 4-1 v AlavésVillarreal 4-1 Alavés | Spanish La Liga |
| 9 | Thu 31 Oct 2019 | 1-2 v EibarEibar 2-1 Villarreal | Spanish La Liga |
| 10 | Sun 3 Nov 2019 | 0-0 v Athletic BilbaoVillarreal 0-0 Athletic Bilbao | Spanish La Liga |
| 11 | Sun 10 Nov 2019 | 1-3 v MallorcaMallorca 3-1 Villarreal | Spanish La Liga |
| 12 | Sun 24 Nov 2019 | 1-3 v Celta VigoVillarreal 1-3 Celta Vigo | Spanish La Liga |
| 13 | Sat 30 Nov 2019 | 1-2 v ValenciaValencia 2-1 Villarreal | Spanish La Liga |
| 14 | Fri 6 Dec 2019 | 0-0 v Atlético MadridVillarreal 0-0 Atlético Madrid | Spanish La Liga |
| 15 | Sun 15 Dec 2019 | 2-1 v SevillaSevilla 1-2 Villarreal | Spanish La Liga |
| 16 | Sat 21 Dec 2019 | 1-0 v GetafeVillarreal 1-0 Getafe | Spanish La Liga |
| 17 | Sun 5 Jan 2020 | 2-1 v Real SociedadReal Sociedad 1-2 Villarreal | Spanish La Liga |
| 18 | Sun 19 Jan 2020 | 1-2 v EspanyolVillarreal 1-2 Espanyol | Spanish La Liga |
| 19 | Sat 25 Jan 2020 | 2-1 v AlavésAlavés 1-2 Villarreal | Spanish La Liga |
| 20 | Sat 15 Feb 2020 | 2-1 v LevanteVillarreal 2-1 Levante | Spanish La Liga |
| 21 | Sun 23 Feb 2020 | 1-3 v Atlético MadridAtlético Madrid 3-1 Villarreal | Spanish La Liga |
| 22 | Sun 1 Mar 2020 | 0-1 v Athletic BilbaoAthletic Bilbao 1-0 Villarreal | Spanish La Liga |
| 23 | Sun 8 Mar 2020 | 1-2 v LeganésVillarreal 1-2 Leganés | Spanish La Liga |
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