| 1 | Fri 25 Jul | 161-1 v Royal AntwerpRoyal Antwerp 1-1 Union Saint-Gilloise | Belgian Pro League |
| 2 | Sat 9 Aug | 16 3-2 v KAA GentKAA Gent 2-3 Union Saint-Gilloise | Belgian Pro League |
| 3 | Sat 16 Aug | 163-0 v Standard LiègeUnion Saint-Gilloise 3-0 Standard Liège | Belgian Pro League |
| 4 | Sun 24 Aug | 160-0 v La LouvièreLa Louvière 0-0 Union Saint-Gilloise | Belgian Pro League |
| 5 | Sun 31 Aug | 162-0 v RSC AnderlechtUnion Saint-Gilloise 2-0 RSC Anderlecht | Belgian Pro League |
| 6 | Tue 16 Sep | 163-1 v PSV EindhovenPSV Eindhoven 1-3 Union Saint-Gilloise | UEFA Champions League Matchday 1 |
| 7 | Sun 21 Sep | 162-1 v KRC GenkKRC Genk 1-2 Union Saint-Gilloise | Belgian Pro League |
| 8 | Sat 27 Sep | 162-0 v KVC WesterloUnion Saint-Gilloise 2-0 KVC Westerlo | Belgian Pro League |
| 9 | Wed 1 Oct | 16 0-4 v Newcastle UnitedUnion Saint-Gilloise 0-4 Newcastle United | UEFA Champions League Matchday 2 |
| 10 | Sun 5 Oct | 160-1 v Club BruggeClub Brugge 1-0 Union Saint-Gilloise | Belgian Pro League |
| 11 | Sat 18 Oct | 163-1 v Sporting de CharleroiUnion Saint-Gilloise 3-1 Sporting de Charleroi | Belgian Pro League |
| 12 | Tue 21 Oct | 160-4 v Inter MilanUnion Saint-Gilloise 0-4 Inter Milan | UEFA Champions League Matchday 3 |
| 13 | Sun 26 Oct | 162-0 v Sint-Truidense VVUnion Saint-Gilloise 2-0 Sint-Truidense VV | Belgian Pro League |
| 14 | Sat 1 Nov | 16 4-1 v SV Zulte WaregemSV Zulte Waregem 1-4 Union Saint-Gilloise | Belgian Pro League |
| 15 | Tue 4 Nov | 161-3 v Atlético MadridAtlético Madrid 3-1 Union Saint-Gilloise | UEFA Champions League Matchday 4 |
| 16 | Sun 9 Nov | 161-1 v MechelenMechelen 1-1 Union Saint-Gilloise | Belgian Pro League |
| 17 | Sat 22 Nov | 162-0 v Cercle BruggeUnion Saint-Gilloise 2-0 Cercle Brugge | Belgian Pro League |
| 18 | Tue 25 Nov | 161-0 v GalatasarayGalatasaray 0-1 Union Saint-Gilloise | UEFA Champions League Matchday 5 |
| 19 | Sun 30 Nov | 16 0-1 v RSC AnderlechtRSC Anderlecht 1-0 Union Saint-Gilloise | Belgian Pro League |
| 20 | Sat 6 Dec | 161-1 v KAA GentUnion Saint-Gilloise 1-1 KAA Gent | Belgian Pro League |
| 21 | Tue 9 Dec | 16 2-3 v Olympique MarseilleUnion Saint-Gilloise 2-3 Olympique Marseille | UEFA Champions League Matchday 6 |
| 22 | Sun 14 Dec | 161-1 v Sporting de CharleroiSporting de Charleroi 1-1 Union Saint-Gilloise | Belgian Pro League |
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