| 1 | Mon 19 Aug | 21 2-2 v Atlético MadridVillarreal 2-2 Atlético Madrid |
| 2 | Fri 23 Aug | 212-1 v SevillaSevilla 1-2 Villarreal |
| 3 | Mon 26 Aug | 21 4-3 v Celta VigoVillarreal 4-3 Celta Vigo |
| 4 | Sat 31 Aug | 21 1-1 v ValenciaValencia 1-1 Villarreal |
| 5 | Sat 14 Sep | 212-1 v MallorcaMallorca 1-2 Villarreal |
| 6 | Sun 22 Sep | 211-5 v BarcelonaVillarreal 1-5 Barcelona |
| 7 | Sat 5 Oct | 210-2 v Real MadridReal Madrid 2-0 Villarreal |
| 8 | Sun 20 Oct | 211-1 v GetafeVillarreal 1-1 Getafe |
| 9 | Sat 26 Oct | 212-1 v Real ValladolidReal Valladolid 1-2 Villarreal |
| 10 | Sat 9 Nov | 213-0 v AlavésVillarreal 3-0 Alavés |
| 11 | Sun 24 Nov | 212-2 v OsasunaOsasuna 2-2 Villarreal |
| 12 | Sun 1 Dec | 212-2 v GironaVillarreal 2-2 Girona |
| 13 | Sun 8 Dec | 210-2 v Athletic BilbaoAthletic Bilbao 2-0 Villarreal |
| 14 | Sun 15 Dec | 21 1-2 v Real BetisVillarreal 1-2 Real Betis |
| 15 | Wed 18 Dec | 21 1-1 v Rayo VallecanoVillarreal 1-1 Rayo Vallecano |
| 16 | Sun 22 Dec | 21 5-2 v LeganésLeganés 2-5 Villarreal |
| 17 | Mon 20 Jan | 214-0 v MallorcaVillarreal 4-0 Mallorca |
| 18 | Sat 25 Jan | 21 1-1 v Atlético MadridAtlético Madrid 1-1 Villarreal |
| 19 | Sat 1 Feb | 215-1 v Real ValladolidVillarreal 5-1 Real Valladolid |
| 20 | Sat 8 Feb | 212-1 v Las PalmasLas Palmas 1-2 Villarreal |
| 21 | Sat 15 Feb | 211-1 v ValenciaVillarreal 1-1 Valencia |
| 22 | Sat 22 Feb | 21 1-0 v Rayo VallecanoRayo Vallecano 0-1 Villarreal |
| 23 | Sat 8 Mar | 21 0-1 v AlavésAlavés 1-0 Villarreal |
| 24 | Sat 15 Mar | 211-2 v Real MadridVillarreal 1-2 Real Madrid |
| 25 | Sun 30 Mar | 212-1 v GetafeGetafe 1-2 Villarreal |
| 26 | Sun 6 Apr | 210-0 v Athletic BilbaoVillarreal 0-0 Athletic Bilbao |
| 27 | Sun 13 Apr | 212-1 v Real BetisReal Betis 1-2 Villarreal |
| 28 | Sun 20 Apr | 21 2-2 v Real SociedadVillarreal 2-2 Real Sociedad |
| 29 | Wed 23 Apr | 210-3 v Celta VigoCelta Vigo 3-0 Villarreal |
| 30 | Sun 27 Apr | 21 1-0 v EspanyolVillarreal 1-0 Espanyol |
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