| 1 | Sun 31 Aug | 211-1 v Celta VigoCelta Vigo 1-1 Villarreal |
| 2 | Sat 13 Sep | 210-2 v Atlético MadridAtlético Madrid 2-0 Villarreal |
| 3 | Sat 20 Sep | 212-1 v OsasunaVillarreal 2-1 Osasuna |
| 4 | Tue 23 Sep | 212-1 v SevillaSevilla 1-2 Villarreal |
| 5 | Sat 27 Sep | 211-0 v Athletic BilbaoVillarreal 1-0 Athletic Bilbao |
| 6 | Sat 4 Oct | 211-3 v Real MadridReal Madrid 3-1 Villarreal |
| 7 | Sat 18 Oct | 212-2 v Real BetisVillarreal 2-2 Real Betis |
| 8 | Sat 1 Nov | 214-0 v Rayo VallecanoVillarreal 4-0 Rayo Vallecano |
| 9 | Sat 8 Nov | 212-0 v EspanyolEspanyol 0-2 Villarreal |
| 10 | Sat 22 Nov | 212-1 v MallorcaVillarreal 2-1 Mallorca |
| 11 | Sun 30 Nov | 213-2 v Real SociedadReal Sociedad 2-3 Villarreal |
| 12 | Sat 6 Dec | 212-0 v GetafeVillarreal 2-0 Getafe |
| 13 | Sun 21 Dec | 210-2 v BarcelonaVillarreal 0-2 Barcelona |
| 14 | Sat 3 Jan | 213-1 v ElcheElche 1-3 Villarreal |
| 15 | Sat 10 Jan | 213-1 v AlavésVillarreal 3-1 Alavés |
| 16 | Sat 24 Jan | 210-2 v Real MadridVillarreal 0-2 Real Madrid |
| 17 | Sat 31 Jan | 212-2 v OsasunaOsasuna 2-2 Villarreal |
| 18 | Mon 9 Feb | 214-1 v EspanyolVillarreal 4-1 Espanyol |
| 19 | Sat 14 Feb | 21 1-2 v GetafeGetafe 2-1 Villarreal |
| 20 | Wed 18 Feb | 211-0 v LevanteLevante 0-1 Villarreal |
| 21 | Sat 28 Feb | 211-4 v BarcelonaBarcelona 4-1 Villarreal |
| 22 | Fri 13 Mar | 211-1 v AlavésAlavés 1-1 Villarreal |
| 23 | Fri 20 Mar | 213-1 v Real SociedadVillarreal 3-1 Real Sociedad |
| 24 | Sun 12 Apr | 212-1 v Athletic BilbaoAthletic Bilbao 1-2 Villarreal |
| 25 | Thu 23 Apr | 211-1 v Real OviedoReal Oviedo 1-1 Villarreal |
| 26 | Sun 10 May | 211-1 v MallorcaMallorca 1-1 Villarreal |
| 27 | Sun 17 May | 210-2 v Rayo VallecanoRayo Vallecano 2-0 Villarreal |
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