| 1 | Fri 15 Aug | 33-1 v GironaGirona 1-3 Rayo Vallecano |
| 2 | Mon 25 Aug | 3 0-1 v Athletic BilbaoAthletic Bilbao 1-0 Rayo Vallecano |
| 3 | Sun 31 Aug | 3 1-1 v BarcelonaRayo Vallecano 1-1 Barcelona |
| 4 | Sun 14 Sep | 30-2 v OsasunaOsasuna 2-0 Rayo Vallecano |
| 5 | Sun 21 Sep | 31-1 v Celta VigoRayo Vallecano 1-1 Celta Vigo |
| 6 | Wed 24 Sep | 3 2-3 v Atlético MadridAtlético Madrid 3-2 Rayo Vallecano |
| 7 | Sun 28 Sep | 30-1 v SevillaRayo Vallecano 0-1 Sevilla |
| 8 | Sun 5 Oct | 31-0 v Real SociedadReal Sociedad 0-1 Rayo Vallecano |
| 9 | Sun 19 Oct | 33-0 v LevanteLevante 0-3 Rayo Vallecano |
| 10 | Sun 26 Oct | 31-0 v AlavésRayo Vallecano 1-0 Alavés |
| 11 | Sat 1 Nov | 30-4 v VillarrealVillarreal 4-0 Rayo Vallecano |
| 12 | Sun 9 Nov | 30-0 v Real MadridRayo Vallecano 0-0 Real Madrid |
| 13 | Sun 23 Nov | 30-0 v Real OviedoReal Oviedo 0-0 Rayo Vallecano |
| 14 | Mon 1 Dec | 31-1 v ValenciaRayo Vallecano 1-1 Valencia |
| 15 | Sun 7 Dec | 3 0-1 v EspanyolEspanyol 1-0 Rayo Vallecano |
| 16 | Mon 15 Dec | 30-0 v Real BetisRayo Vallecano 0-0 Real Betis |
| 17 | Sun 21 Dec | 30-4 v ElcheElche 4-0 Rayo Vallecano |
| 18 | Fri 2 Jan | 31-1 v GetafeRayo Vallecano 1-1 Getafe |
| 19 | Sun 11 Jan | 32-1 v MallorcaRayo Vallecano 2-1 Mallorca |
| 20 | Sun 18 Jan | 30-3 v Celta VigoCelta Vigo 3-0 Rayo Vallecano |
| 21 | Sat 24 Jan | 31-3 v OsasunaRayo Vallecano 1-3 Osasuna |
| 22 | Sun 1 Feb | 3 1-2 v Real MadridReal Madrid 2-1 Rayo Vallecano |
| 23 | Sat 21 Feb | 31-1 v Real BetisReal Betis 1-1 Rayo Vallecano |
| 24 | Wed 4 Mar | 33-0 v Real OviedoRayo Vallecano 3-0 Real Oviedo |
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