| 1 | Mon 19 Aug | 132-2 v Atlético MadridVillarreal 2-2 Atlético Madrid |
| 2 | Fri 23 Aug | 132-1 v SevillaSevilla 1-2 Villarreal |
| 3 | Mon 26 Aug | 134-3 v Celta VigoVillarreal 4-3 Celta Vigo |
| 4 | Sat 31 Aug | 131-1 v ValenciaValencia 1-1 Villarreal |
| 5 | Sat 14 Sep | 132-1 v MallorcaMallorca 1-2 Villarreal |
| 6 | Sun 22 Sep | 131-5 v BarcelonaVillarreal 1-5 Barcelona |
| 7 | Thu 26 Sep | 13 2-1 v EspanyolEspanyol 1-2 Villarreal |
| 8 | Mon 30 Sep | 133-1 v Las PalmasVillarreal 3-1 Las Palmas |
| 9 | Sat 5 Oct | 130-2 v Real MadridReal Madrid 2-0 Villarreal |
| 10 | Sun 20 Oct | 131-1 v GetafeVillarreal 1-1 Getafe |
| 11 | Sat 26 Oct | 132-1 v Real ValladolidReal Valladolid 1-2 Villarreal |
| 12 | Sat 9 Nov | 133-0 v AlavésVillarreal 3-0 Alavés |
| 13 | Sun 24 Nov | 132-2 v OsasunaOsasuna 2-2 Villarreal |
| 14 | Sun 1 Dec | 132-2 v GironaVillarreal 2-2 Girona |
| 15 | Sun 8 Dec | 130-2 v Athletic BilbaoAthletic Bilbao 2-0 Villarreal |
| 16 | Sat 1 Feb | 135-1 v Real ValladolidVillarreal 5-1 Real Valladolid |
| 17 | Sat 8 Feb | 132-1 v Las PalmasLas Palmas 1-2 Villarreal |
| 18 | Sat 15 Feb | 131-1 v ValenciaVillarreal 1-1 Valencia |
| 19 | Sat 22 Feb | 13 1-0 v Rayo VallecanoRayo Vallecano 0-1 Villarreal |
| 20 | Sat 8 Mar | 130-1 v AlavésAlavés 1-0 Villarreal |
| 21 | Sat 15 Mar | 131-2 v Real MadridVillarreal 1-2 Real Madrid |
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