| 1 | Fri 15 Aug | 102-0 v Real OviedoVillarreal 2-0 Real Oviedo |
| 2 | Sun 24 Aug | 105-0 v GironaVillarreal 5-0 Girona |
| 3 | Sun 31 Aug | 101-1 v Celta VigoCelta Vigo 1-1 Villarreal |
| 4 | Sat 13 Sep | 10 0-2 v Atlético MadridAtlético Madrid 2-0 Villarreal |
| 5 | Tue 23 Sep | 102-1 v SevillaSevilla 1-2 Villarreal |
| 6 | Sat 27 Sep | 10 1-0 v Athletic BilbaoVillarreal 1-0 Athletic Bilbao |
| 7 | Sat 4 Oct | 101-3 v Real MadridReal Madrid 3-1 Villarreal |
| 8 | Sat 18 Oct | 102-2 v Real BetisVillarreal 2-2 Real Betis |
| 9 | Sat 25 Oct | 102-0 v ValenciaValencia 0-2 Villarreal |
| 10 | Sat 1 Nov | 104-0 v Rayo VallecanoVillarreal 4-0 Rayo Vallecano |
| 11 | Sun 30 Nov | 103-2 v Real SociedadReal Sociedad 2-3 Villarreal |
| 12 | Sat 6 Dec | 102-0 v GetafeVillarreal 2-0 Getafe |
| 13 | Sun 21 Dec | 100-2 v BarcelonaVillarreal 0-2 Barcelona |
| 14 | Sat 3 Jan | 103-1 v ElcheElche 1-3 Villarreal |
| 15 | Sat 10 Jan | 103-1 v AlavésVillarreal 3-1 Alavés |
| 16 | Sat 17 Jan | 100-2 v Real BetisReal Betis 2-0 Villarreal |
| 17 | Sat 24 Jan | 100-2 v Real MadridVillarreal 0-2 Real Madrid |
| 18 | Sat 31 Jan | 102-2 v OsasunaOsasuna 2-2 Villarreal |
| 19 | Mon 9 Feb | 104-1 v EspanyolVillarreal 4-1 Espanyol |
| 20 | Sat 14 Feb | 101-2 v GetafeGetafe 2-1 Villarreal |
| 21 | Sun 22 Feb | 102-1 v ValenciaVillarreal 2-1 Valencia |
| 22 | Sat 28 Feb | 101-4 v BarcelonaBarcelona 4-1 Villarreal |
| 23 | Sun 8 Mar | 102-1 v ElcheVillarreal 2-1 Elche |
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