| 1 | Sat 13 Sep | 220-2 v Atlético MadridAtlético Madrid 2-0 Villarreal |
| 2 | Sat 18 Oct | 222-2 v Real BetisVillarreal 2-2 Real Betis |
| 3 | Sat 25 Oct | 222-0 v ValenciaValencia 0-2 Villarreal |
| 4 | Sat 1 Nov | 224-0 v Rayo VallecanoVillarreal 4-0 Rayo Vallecano |
| 5 | Sat 8 Nov | 222-0 v EspanyolEspanyol 0-2 Villarreal |
| 6 | Sat 22 Nov | 222-1 v MallorcaVillarreal 2-1 Mallorca |
| 7 | Sun 30 Nov | 22 3-2 v Real SociedadReal Sociedad 2-3 Villarreal |
| 8 | Sat 6 Dec | 222-0 v GetafeVillarreal 2-0 Getafe |
| 9 | Sun 21 Dec | 220-2 v BarcelonaVillarreal 0-2 Barcelona |
| 10 | Sat 3 Jan | 22 3-1 v ElcheElche 1-3 Villarreal |
| 11 | Sat 10 Jan | 223-1 v AlavésVillarreal 3-1 Alavés |
| 12 | Sat 17 Jan | 220-2 v Real BetisReal Betis 2-0 Villarreal |
| 13 | Sat 24 Jan | 220-2 v Real MadridVillarreal 0-2 Real Madrid |
| 14 | Sat 14 Feb | 221-2 v GetafeGetafe 2-1 Villarreal |
| 15 | Wed 18 Feb | 22 1-0 v LevanteLevante 0-1 Villarreal |
| 16 | Sun 22 Feb | 222-1 v ValenciaVillarreal 2-1 Valencia |
| 17 | Sat 28 Feb | 221-4 v BarcelonaBarcelona 4-1 Villarreal |
| 18 | Thu 23 Apr | 221-1 v Real OviedoReal Oviedo 1-1 Villarreal |
| 19 | Sun 26 Apr | 222-1 v Celta VigoVillarreal 2-1 Celta Vigo |
| 20 | Sat 2 May | 225-1 v LevanteVillarreal 5-1 Levante |
| 21 | Sun 10 May | 221-1 v MallorcaMallorca 1-1 Villarreal |
| 22 | Wed 13 May | 22 2-3 v SevillaVillarreal 2-3 Sevilla |
| 23 | Sun 17 May | 220-2 v Rayo VallecanoRayo Vallecano 2-0 Villarreal |
| 24 | Sun 24 May | 225-1 v Atlético MadridVillarreal 5-1 Atlético Madrid |
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