| 1 | Mon 19 Aug | 222-2 v Atlético MadridVillarreal 2-2 Atlético Madrid |
| 2 | Fri 23 Aug | 22 2-1 v SevillaSevilla 1-2 Villarreal |
| 3 | Mon 26 Aug | 224-3 v Celta VigoVillarreal 4-3 Celta Vigo |
| 4 | Sat 31 Aug | 221-1 v ValenciaValencia 1-1 Villarreal |
| 5 | Sat 14 Sep | 222-1 v MallorcaMallorca 1-2 Villarreal |
| 6 | Sun 22 Sep | 22 1-5 v BarcelonaVillarreal 1-5 Barcelona |
| 7 | Thu 26 Sep | 22 2-1 v EspanyolEspanyol 1-2 Villarreal |
| 8 | Sat 9 Nov | 223-0 v AlavésVillarreal 3-0 Alavés |
| 9 | Sun 8 Dec | 220-2 v Athletic BilbaoAthletic Bilbao 2-0 Villarreal |
| 10 | Sun 15 Dec | 221-2 v Real BetisVillarreal 1-2 Real Betis |
| 11 | Wed 18 Dec | 221-1 v Rayo VallecanoVillarreal 1-1 Rayo Vallecano |
| 12 | Sat 25 Jan | 221-1 v Atlético MadridAtlético Madrid 1-1 Villarreal |
| 13 | Sat 1 Feb | 225-1 v Real ValladolidVillarreal 5-1 Real Valladolid |
| 14 | Sat 8 Feb | 222-1 v Las PalmasLas Palmas 1-2 Villarreal |
| 15 | Sat 15 Feb | 221-1 v ValenciaVillarreal 1-1 Valencia |
| 16 | Sat 22 Feb | 221-0 v Rayo VallecanoRayo Vallecano 0-1 Villarreal |
| 17 | Sat 8 Mar | 220-1 v AlavésAlavés 1-0 Villarreal |
| 18 | Sat 15 Mar | 221-2 v Real MadridVillarreal 1-2 Real Madrid |
| 19 | Sun 30 Mar | 222-1 v GetafeGetafe 1-2 Villarreal |
| 20 | Sun 6 Apr | 220-0 v Athletic BilbaoVillarreal 0-0 Athletic Bilbao |
| 21 | Sun 13 Apr | 222-1 v Real BetisReal Betis 1-2 Villarreal |
| 22 | Sun 20 Apr | 222-2 v Real SociedadVillarreal 2-2 Real Sociedad |
| 23 | Sun 27 Apr | 221-0 v EspanyolVillarreal 1-0 Espanyol |
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