| 1 | Fri 15 Aug | 242-0 v Real OviedoVillarreal 2-0 Real Oviedo |
| 2 | Sat 13 Sep | 24 0-2 v Atlético MadridAtlético Madrid 2-0 Villarreal |
| 3 | Sat 20 Sep | 242-1 v OsasunaVillarreal 2-1 Osasuna |
| 4 | Tue 23 Sep | 24 2-1 v SevillaSevilla 1-2 Villarreal |
| 5 | Sat 27 Sep | 241-0 v Athletic BilbaoVillarreal 1-0 Athletic Bilbao |
| 6 | Sat 4 Oct | 241-3 v Real MadridReal Madrid 3-1 Villarreal |
| 7 | Sat 18 Oct | 242-2 v Real BetisVillarreal 2-2 Real Betis |
| 8 | Sat 1 Nov | 244-0 v Rayo VallecanoVillarreal 4-0 Rayo Vallecano |
| 9 | Sat 8 Nov | 242-0 v EspanyolEspanyol 0-2 Villarreal |
| 10 | Sat 22 Nov | 242-1 v MallorcaVillarreal 2-1 Mallorca |
| 11 | Sun 30 Nov | 24 3-2 v Real SociedadReal Sociedad 2-3 Villarreal |
| 12 | Sat 3 Jan | 243-1 v ElcheElche 1-3 Villarreal |
| 13 | Sat 10 Jan | 243-1 v AlavésVillarreal 3-1 Alavés |
| 14 | Sat 17 Jan | 24 0-2 v Real BetisReal Betis 2-0 Villarreal |
| 15 | Sat 24 Jan | 240-2 v Real MadridVillarreal 0-2 Real Madrid |
| 16 | Sat 31 Jan | 24 2-2 v OsasunaOsasuna 2-2 Villarreal |
| 17 | Sat 14 Feb | 241-2 v GetafeGetafe 2-1 Villarreal |
| 18 | Wed 18 Feb | 241-0 v LevanteLevante 0-1 Villarreal |
| 19 | Sun 22 Feb | 242-1 v ValenciaVillarreal 2-1 Valencia |
| 20 | Sat 28 Feb | 24 1-4 v BarcelonaBarcelona 4-1 Villarreal |
| 21 | Fri 13 Mar | 241-1 v AlavésAlavés 1-1 Villarreal |
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