| 1 | Sat 11 Aug 2012 | 111-1 v Hull CityHull City 1-1 Rotherham United | Capital One Cup First Round |
| 2 | Tue 21 Aug 2012 | 111-2 v Northampton TownNorthampton Town 2-1 Rotherham United | npower League Two |
| 3 | Sat 25 Aug 2012 | 111-1 v ChesterfieldChesterfield 1-1 Rotherham United | npower League Two |
| 4 | Sat 1 Sep 2012 | 114-0 v Bradford CityRotherham United 4-0 Bradford City | npower League Two |
| 5 | Tue 4 Sep 2012 | 110-1 v York CityRotherham United 0-1 York City | Johnstone's Paint Trophy First Round |
| 6 | Sat 8 Sep 2012 | 112-6 v Port ValePort Vale 6-2 Rotherham United | npower League Two |
| 7 | Sat 15 Sep 2012 | 111-0 v Torquay UnitedRotherham United 1-0 Torquay United | npower League Two |
| 8 | Tue 18 Sep 2012 | 112-3 v RochdaleRotherham United 2-3 Rochdale | npower League Two |
| 9 | Sat 29 Sep 2012 | 113-1 v Oxford UnitedRotherham United 3-1 Oxford United | npower League Two |
| 10 | Sat 6 Oct 2012 | 110-0 v York CityYork City 0-0 Rotherham United | npower League Two |
| 11 | Sat 27 Oct 2012 | 141-0 v Plymouth ArgyleRotherham United 1-0 Plymouth Argyle | npower League Two |
| 12 | Tue 6 Nov 2012 | 111-1 v Fleetwood TownFleetwood Town 1-1 Rotherham United | npower League Two |
| 13 | Sat 10 Nov 2012 | 110-5 v Dagenham & RedbridgeDagenham & Redbridge 5-0 Rotherham United | npower League Two |
| 14 | Tue 20 Nov 2012 | 112-3 v Wycombe WanderersRotherham United 2-3 Wycombe Wanderers | npower League Two |
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