| 1 | Sun 27 Sep 2020 | 161-1 v Celta VigoReal Valladolid 1-1 Celta Vigo | Spanish La Liga |
| 2 | Wed 30 Sep 2020 | 160-1 v Real MadridReal Madrid 1-0 Real Valladolid | Spanish La Liga |
| 3 | Sat 3 Oct 2020 | 161-2 v EibarReal Valladolid 1-2 Eibar | Spanish La Liga |
| 4 | Sun 18 Oct 2020 | 162-2 v HuescaHuesca 2-2 Real Valladolid | Spanish La Liga |
| 5 | Sun 25 Oct 2020 | 160-2 v AlavésReal Valladolid 0-2 Alavés | Spanish La Liga |
| 6 | Mon 2 Nov 2020 | 160-2 v VillarrealVillarreal 2-0 Real Valladolid | Spanish La Liga |
| 7 | Sun 8 Nov 2020 | 162-1 v Athletic BilbaoReal Valladolid 2-1 Athletic Bilbao | Spanish La Liga |
| 8 | Sun 22 Nov 2020 | 163-1 v GranadaGranada 1-3 Real Valladolid | Spanish La Liga |
| 9 | Fri 27 Nov 2020 | 161-1 v LevanteReal Valladolid 1-1 Levante | Spanish La Liga |
| 10 | Sat 5 Dec 2020 | 160-2 v Atlético MadridAtlético Madrid 2-0 Real Valladolid | Spanish La Liga |
| 11 | Fri 11 Dec 2020 | 163-2 v OsasunaReal Valladolid 3-2 Osasuna | Spanish La Liga |
| 12 | Sat 19 Dec 2020 | 16 1-1 v SevillaSevilla 1-1 Real Valladolid | Spanish La Liga |
| 13 | Tue 22 Dec 2020 | 160-3 v BarcelonaReal Valladolid 0-3 Barcelona | Spanish La Liga |
| 14 | Mon 5 Apr 2021 | 160-1 v BarcelonaBarcelona 1-0 Real Valladolid | Spanish La Liga |
| 15 | Sun 11 Apr 2021 | 161-2 v GranadaReal Valladolid 1-2 Granada | Spanish La Liga |
| 16 | Wed 21 Apr 2021 | 161-1 v ElcheElche 1-1 Real Valladolid | Spanish La Liga |
| 17 | Sat 24 Apr 2021 | 161-1 v CádizReal Valladolid 1-1 Cádiz | Spanish La Liga |
| 18 | Wed 28 Apr 2021 | 162-2 v Athletic BilbaoAthletic Bilbao 2-2 Real Valladolid | Spanish La Liga |
| 19 | Sun 2 May 2021 | 161-1 v Real BetisReal Valladolid 1-1 Real Betis | Spanish La Liga |
| 20 | Thu 13 May 2021 | 160-2 v VillarrealReal Valladolid 0-2 Villarreal | Spanish La Liga |
| 21 | Sun 16 May 2021 | 16 1-4 v Real SociedadReal Sociedad 4-1 Real Valladolid | Spanish La Liga |
| 22 | Sat 22 May 2021 | 16 1-2 v Atlético MadridReal Valladolid 1-2 Atlético Madrid | Spanish La Liga |
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