| 1 | Fri 15 Aug | 233-1 v GironaGirona 1-3 Rayo Vallecano | Spanish La Liga |
| 2 | Thu 28 Aug | 234-0 v Neman GrodnoRayo Vallecano 4-0 Neman Grodno | UEFA Europa Conference League |
| 3 | Sun 31 Aug | 231-1 v BarcelonaRayo Vallecano 1-1 Barcelona | Spanish La Liga |
| 4 | Sun 21 Sep | 231-1 v Celta VigoRayo Vallecano 1-1 Celta Vigo | Spanish La Liga |
| 5 | Wed 24 Sep | 232-3 v Atlético MadridAtlético Madrid 3-2 Rayo Vallecano | Spanish La Liga |
| 6 | Sun 28 Sep | 230-1 v SevillaRayo Vallecano 0-1 Sevilla | Spanish La Liga |
| 7 | Sun 5 Oct | 231-0 v Real SociedadReal Sociedad 0-1 Rayo Vallecano | Spanish La Liga |
| 8 | Sun 19 Oct | 233-0 v LevanteLevante 0-3 Rayo Vallecano | Spanish La Liga |
| 9 | Sun 26 Oct | 231-0 v AlavésRayo Vallecano 1-0 Alavés | Spanish La Liga |
| 10 | Sat 1 Nov | 230-4 v VillarrealVillarreal 4-0 Rayo Vallecano | Spanish La Liga |
| 11 | Thu 6 Nov | 23 3-2 v Lech PoznańRayo Vallecano 3-2 Lech Poznań | UEFA Europa Conference League Matchday 3 |
| 12 | Sun 9 Nov | 230-0 v Real MadridRayo Vallecano 0-0 Real Madrid | Spanish La Liga |
| 13 | Sun 23 Nov | 230-0 v Real OviedoReal Oviedo 0-0 Rayo Vallecano | Spanish La Liga |
| 14 | Thu 27 Nov | 23 1-2 v Slovan BratislavaSlovan Bratislava 2-1 Rayo Vallecano | UEFA Europa Conference League Matchday 4 |
| 15 | Mon 1 Dec | 231-1 v ValenciaRayo Vallecano 1-1 Valencia | Spanish La Liga |
| 16 | Sun 7 Dec | 23 0-1 v EspanyolEspanyol 1-0 Rayo Vallecano | Spanish La Liga |
| 17 | Thu 11 Dec | 232-1 v Jagiellonia BiałystokJagiellonia Białystok 1-2 Rayo Vallecano | UEFA Europa Conference League Matchday 5 |
| 18 | Mon 15 Dec | 230-0 v Real BetisRayo Vallecano 0-0 Real Betis | Spanish La Liga |
| 19 | Thu 18 Dec | 233-0 v Drita GjilanRayo Vallecano 3-0 Drita Gjilan | UEFA Europa Conference League Matchday 6 |
| 20 | Sun 21 Dec | 230-4 v ElcheElche 4-0 Rayo Vallecano | Spanish La Liga |
| 21 | Fri 2 Jan | 231-1 v GetafeRayo Vallecano 1-1 Getafe | Spanish La Liga |
| 22 | Sun 11 Jan | 23 2-1 v MallorcaRayo Vallecano 2-1 Mallorca | Spanish La Liga |
| 23 | Sat 24 Jan | 231-3 v OsasunaRayo Vallecano 1-3 Osasuna | Spanish La Liga |
| 24 | Sun 1 Feb | 23 1-2 v Real MadridReal Madrid 2-1 Rayo Vallecano | Spanish La Liga |
| 25 | Sun 15 Feb | 233-0 v Atlético MadridRayo Vallecano 3-0 Atlético Madrid | Spanish La Liga |
| 26 | Sat 21 Feb | 231-1 v Real BetisReal Betis 1-1 Rayo Vallecano | Spanish La Liga |
| 27 | Sat 28 Feb | 231-1 v Athletic BilbaoRayo Vallecano 1-1 Athletic Bilbao | Spanish La Liga |
| 28 | Sun 8 Mar | 231-1 v SevillaSevilla 1-1 Rayo Vallecano | Spanish La Liga |
| 29 | Thu 12 Mar | 233-1 v SamsunsporSamsunspor 1-3 Rayo Vallecano | UEFA Europa Conference League Round of 16 |
| 30 | Mon 16 Mar | 231-1 v LevanteRayo Vallecano 1-1 Levante | Spanish La Liga |
| 31 | Thu 19 Mar | 230-1 v SamsunsporRayo Vallecano 0-1 Samsunspor | UEFA Europa Conference League Round of 16 |
| 32 | Sun 22 Mar | 23 0-1 v BarcelonaBarcelona 1-0 Rayo Vallecano | Spanish La Liga |
| 33 | Fri 3 Apr | 231-0 v ElcheRayo Vallecano 1-0 Elche | Spanish La Liga |
| 34 | Thu 9 Apr | 233-0 v AEK FCRayo Vallecano 3-0 AEK FC | UEFA Europa Conference League Quarter Final |
| 35 | Sun 12 Apr | 230-3 v MallorcaMallorca 3-0 Rayo Vallecano | Spanish La Liga |
| 36 | Thu 16 Apr | 231-3 v AEK FCAEK FC 3-1 Rayo Vallecano | UEFA Europa Conference League Quarter Final |
| 37 | Thu 23 Apr | 231-0 v EspanyolRayo Vallecano 1-0 Espanyol | Spanish La Liga |
| 38 | Thu 30 Apr | 231-0 v StrasbourgRayo Vallecano 1-0 Strasbourg | UEFA Europa Conference League Semi Final |
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