| 1 | Sat 13 Aug 2022 | 140-0 v BarcelonaBarcelona 0-0 Rayo Vallecano | Spanish La Liga |
| 2 | Fri 19 Aug 2022 | 142-0 v EspanyolEspanyol 0-2 Rayo Vallecano | Spanish La Liga |
| 3 | Sat 27 Aug 2022 | 140-2 v MallorcaRayo Vallecano 0-2 Mallorca | Spanish La Liga |
| 4 | Sun 4 Sep 2022 | 141-2 v OsasunaOsasuna 2-1 Rayo Vallecano | Spanish La Liga |
| 5 | Sat 8 Oct 2022 | 14 1-3 v AlmeríaAlmería 3-1 Rayo Vallecano | Spanish La Liga |
| 6 | Sat 22 Oct 2022 | 145-1 v CádizRayo Vallecano 5-1 Cádiz | Spanish La Liga |
| 7 | Sat 29 Oct 2022 | 141-0 v SevillaSevilla 0-1 Rayo Vallecano | Spanish La Liga |
| 8 | Thu 10 Nov 2022 | 14 0-0 v Celta VigoRayo Vallecano 0-0 Celta Vigo | Spanish La Liga |
| 9 | Sat 21 Jan 2023 | 140-2 v Real SociedadRayo Vallecano 0-2 Real Sociedad | Spanish La Liga |
| 10 | Mon 6 Feb 2023 | 142-0 v AlmeríaRayo Vallecano 2-0 Almería | Spanish La Liga |
| 11 | Sun 5 Mar 2023 | 140-0 v Athletic BilbaoRayo Vallecano 0-0 Athletic Bilbao | Spanish La Liga |
| 12 | Sat 11 Mar 2023 | 140-3 v Celta VigoCelta Vigo 3-0 Rayo Vallecano | Spanish La Liga |
| 13 | Sat 18 Mar 2023 | 142-2 v GironaRayo Vallecano 2-2 Girona | Spanish La Liga |
| 14 | Mon 3 Apr 2023 | 141-1 v ValenciaValencia 1-1 Rayo Vallecano | Spanish La Liga |
| 15 | Fri 14 Apr 2023 | 142-1 v OsasunaRayo Vallecano 2-1 Osasuna | Spanish La Liga |
| 16 | Sat 22 Apr 2023 | 141-2 v Real SociedadReal Sociedad 2-1 Rayo Vallecano | Spanish La Liga |
| 17 | Sat 29 Apr 2023 | 140-4 v ElcheElche 4-0 Rayo Vallecano | Spanish La Liga |
| 18 | Wed 24 May 2023 | 141-2 v Real MadridReal Madrid 2-1 Rayo Vallecano | Spanish La Liga |
| 19 | Sun 28 May 2023 | 142-1 v VillarrealRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 20 | Sun 4 Jun 2023 | 140-3 v MallorcaMallorca 3-0 Rayo Vallecano | Spanish La Liga |
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