| 1 | Sat 13 Aug 2022 | 200-0 v BarcelonaBarcelona 0-0 Rayo Vallecano | Spanish La Liga |
| 2 | Fri 19 Aug 2022 | 202-0 v EspanyolEspanyol 0-2 Rayo Vallecano | Spanish La Liga |
| 3 | Sat 27 Aug 2022 | 200-2 v MallorcaRayo Vallecano 0-2 Mallorca | Spanish La Liga |
| 4 | Sun 4 Sep 2022 | 201-2 v OsasunaOsasuna 2-1 Rayo Vallecano | Spanish La Liga |
| 5 | Sat 10 Sep 2022 | 20 2-1 v ValenciaRayo Vallecano 2-1 Valencia | Spanish La Liga |
| 6 | Sat 17 Sep 2022 | 202-3 v Athletic BilbaoAthletic Bilbao 3-2 Rayo Vallecano | Spanish La Liga |
| 7 | Mon 3 Oct 2022 | 202-1 v ElcheRayo Vallecano 2-1 Elche | Spanish La Liga |
| 8 | Sat 8 Oct 2022 | 201-3 v AlmeríaAlmería 3-1 Rayo Vallecano | Spanish La Liga |
| 9 | Fri 14 Oct 2022 | 200-0 v GetafeRayo Vallecano 0-0 Getafe | Spanish La Liga |
| 10 | Tue 18 Oct 2022 | 201-1 v Atlético MadridAtlético Madrid 1-1 Rayo Vallecano | Spanish La Liga |
| 11 | Sat 22 Oct 2022 | 205-1 v CádizRayo Vallecano 5-1 Cádiz | Spanish La Liga |
| 12 | Sat 29 Oct 2022 | 201-0 v SevillaSevilla 0-1 Rayo Vallecano | Spanish La Liga |
| 13 | Mon 7 Nov 2022 | 20 3-2 v Real MadridRayo Vallecano 3-2 Real Madrid | Spanish La Liga |
| 14 | Thu 10 Nov 2022 | 200-0 v Celta VigoRayo Vallecano 0-0 Celta Vigo | Spanish La Liga |
| 15 | Thu 29 Dec 2022 | 202-2 v GironaGirona 2-2 Rayo Vallecano | Spanish La Liga |
| 16 | Sun 8 Jan 2023 | 201-2 v Real BetisRayo Vallecano 1-2 Real Betis | Spanish La Liga |
| 17 | Sat 14 Jan 2023 | 201-0 v Real ValladolidReal Valladolid 0-1 Rayo Vallecano | Spanish La Liga |
| 18 | Sat 21 Jan 2023 | 200-2 v Real SociedadRayo Vallecano 0-2 Real Sociedad | Spanish La Liga |
| 19 | Mon 30 Jan 2023 | 201-0 v VillarrealVillarreal 0-1 Rayo Vallecano | Spanish La Liga |
| 20 | Mon 6 Feb 2023 | 20 2-0 v AlmeríaRayo Vallecano 2-0 Almería | Spanish La Liga |
| 21 | Sun 12 Feb 2023 | 20 1-1 v GetafeGetafe 1-1 Rayo Vallecano | Spanish La Liga |
| 22 | Sun 19 Feb 2023 | 201-1 v SevillaRayo Vallecano 1-1 Sevilla | Spanish La Liga |
| 23 | Sat 25 Feb 2023 | 200-1 v CádizCádiz 1-0 Rayo Vallecano | Spanish La Liga |
| 24 | Sun 5 Mar 2023 | 200-0 v Athletic BilbaoRayo Vallecano 0-0 Athletic Bilbao | Spanish La Liga |
| 25 | Sat 11 Mar 2023 | 20 0-3 v Celta VigoCelta Vigo 3-0 Rayo Vallecano | Spanish La Liga |
| 26 | Mon 3 Apr 2023 | 20 1-1 v ValenciaValencia 1-1 Rayo Vallecano | Spanish La Liga |
| 27 | Sun 9 Apr 2023 | 201-2 v Atlético MadridRayo Vallecano 1-2 Atlético Madrid | Spanish La Liga |
| 28 | Fri 14 Apr 2023 | 202-1 v OsasunaRayo Vallecano 2-1 Osasuna | Spanish La Liga |
| 29 | Sat 22 Apr 2023 | 201-2 v Real SociedadReal Sociedad 2-1 Rayo Vallecano | Spanish La Liga |
| 30 | Wed 26 Apr 2023 | 202-1 v BarcelonaRayo Vallecano 2-1 Barcelona | Spanish La Liga |
| 31 | Sat 29 Apr 2023 | 200-4 v ElcheElche 4-0 Rayo Vallecano | Spanish La Liga |
| 32 | Thu 4 May 2023 | 202-1 v Real ValladolidRayo Vallecano 2-1 Real Valladolid | Spanish La Liga |
| 33 | Mon 15 May 2023 | 201-3 v Real BetisReal Betis 3-1 Rayo Vallecano | Spanish La Liga |
| 34 | Sun 21 May 2023 | 201-2 v EspanyolRayo Vallecano 1-2 Espanyol | Spanish La Liga |
| 35 | Wed 24 May 2023 | 201-2 v Real MadridReal Madrid 2-1 Rayo Vallecano | Spanish La Liga |
| 36 | Sun 28 May 2023 | 202-1 v VillarrealRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 37 | Sun 4 Jun 2023 | 200-3 v MallorcaMallorca 3-0 Rayo Vallecano | Spanish La Liga |
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