| 1 | Sat 17 Sep 2022 | 162-3 v Athletic BilbaoAthletic Bilbao 3-2 Rayo Vallecano | Spanish La Liga |
| 2 | Tue 18 Oct 2022 | 161-1 v Atlético MadridAtlético Madrid 1-1 Rayo Vallecano | Spanish La Liga |
| 3 | Thu 29 Dec 2022 | 162-2 v GironaGirona 2-2 Rayo Vallecano | Spanish La Liga |
| 4 | Sat 14 Jan 2023 | 161-0 v Real ValladolidReal Valladolid 0-1 Rayo Vallecano | Spanish La Liga |
| 5 | Sun 5 Mar 2023 | 16 0-0 v Athletic BilbaoRayo Vallecano 0-0 Athletic Bilbao | Spanish La Liga |
| 6 | Sat 18 Mar 2023 | 162-2 v GironaRayo Vallecano 2-2 Girona | Spanish La Liga |
| 7 | Mon 3 Apr 2023 | 161-1 v ValenciaValencia 1-1 Rayo Vallecano | Spanish La Liga |
| 8 | Sun 9 Apr 2023 | 161-2 v Atlético MadridRayo Vallecano 1-2 Atlético Madrid | Spanish La Liga |
| 9 | Fri 14 Apr 2023 | 162-1 v OsasunaRayo Vallecano 2-1 Osasuna | Spanish La Liga |
| 10 | Sat 22 Apr 2023 | 161-2 v Real SociedadReal Sociedad 2-1 Rayo Vallecano | Spanish La Liga |
| 11 | Wed 26 Apr 2023 | 162-1 v BarcelonaRayo Vallecano 2-1 Barcelona | Spanish La Liga |
| 12 | Thu 4 May 2023 | 162-1 v Real ValladolidRayo Vallecano 2-1 Real Valladolid | Spanish La Liga |
| 13 | Mon 15 May 2023 | 16 1-3 v Real BetisReal Betis 3-1 Rayo Vallecano | Spanish La Liga |
| 14 | Sun 28 May 2023 | 162-1 v VillarrealRayo Vallecano 2-1 Villarreal | Spanish La Liga |
| 15 | Sun 4 Jun 2023 | 160-3 v MallorcaMallorca 3-0 Rayo Vallecano | Spanish La Liga |
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