| 1 | Sun 15 Aug 2021 | 100-3 v SevillaSevilla 3-0 Rayo Vallecano | Spanish La Liga |
| 2 | Sun 29 Aug 2021 | 104-0 v GranadaRayo Vallecano 4-0 Granada | Spanish La Liga |
| 3 | Sat 11 Sep 2021 | 101-1 v LevanteLevante 1-1 Rayo Vallecano | Spanish La Liga |
| 4 | Sat 18 Sep 2021 | 10 3-0 v GetafeRayo Vallecano 3-0 Getafe | Spanish La Liga |
| 5 | Sat 2 Oct 2021 | 100-1 v OsasunaOsasuna 1-0 Rayo Vallecano | Spanish La Liga |
| 6 | Sun 24 Oct 2021 | 102-3 v Real BetisReal Betis 3-2 Rayo Vallecano | Spanish La Liga |
| 7 | Mon 1 Nov 2021 | 100-0 v Celta VigoRayo Vallecano 0-0 Celta Vigo | Spanish La Liga |
| 8 | Sat 6 Nov 2021 | 101-2 v Real MadridReal Madrid 2-1 Rayo Vallecano | Spanish La Liga |
| 9 | Mon 22 Nov 2021 | 103-1 v MallorcaRayo Vallecano 3-1 Mallorca | Spanish La Liga |
| 10 | Sat 27 Nov 2021 | 101-1 v ValenciaValencia 1-1 Rayo Vallecano | Spanish La Liga |
| 11 | Sun 12 Dec 2021 | 100-2 v VillarrealVillarreal 2-0 Rayo Vallecano | Spanish La Liga |
| 12 | Sun 9 Jan 2022 | 101-1 v Real BetisRayo Vallecano 1-1 Real Betis | Spanish La Liga |
| 13 | Sun 23 Jan 2022 | 100-1 v Athletic BilbaoRayo Vallecano 0-1 Athletic Bilbao | Spanish La Liga |
| 14 | Sat 12 Feb 2022 | 100-3 v OsasunaRayo Vallecano 0-3 Osasuna | Spanish La Liga |
| 15 | Fri 18 Feb 2022 | 101-2 v ElcheElche 2-1 Rayo Vallecano | Spanish La Liga |
| 16 | Sat 26 Feb 2022 | 10 0-1 v Real MadridRayo Vallecano 0-1 Real Madrid | Spanish La Liga |
| 17 | Sun 6 Mar 2022 | 100-2 v CádizCádiz 2-0 Rayo Vallecano | Spanish La Liga |
| 18 | Sun 13 Mar 2022 | 101-1 v SevillaRayo Vallecano 1-1 Sevilla | Spanish La Liga |
| 19 | Sat 19 Mar 2022 | 100-1 v Atlético MadridRayo Vallecano 0-1 Atlético Madrid | Spanish La Liga |
| 20 | Mon 11 Apr 2022 | 101-1 v ValenciaRayo Vallecano 1-1 Valencia | Spanish La Liga |
| 21 | Sat 16 Apr 2022 | 100-1 v AlavésAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 22 | Sun 8 May 2022 | 100-0 v GetafeGetafe 0-0 Rayo Vallecano | Spanish La Liga |
| 23 | Thu 12 May 2022 | 101-5 v VillarrealRayo Vallecano 1-5 Villarreal | Spanish La Liga |
| 24 | Sun 15 May 2022 | 101-2 v MallorcaMallorca 2-1 Rayo Vallecano | Spanish La Liga |
| 25 | Fri 20 May 2022 | 102-4 v LevanteRayo Vallecano 2-4 Levante | Spanish La Liga |
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