| 1 | Sun 22 Sep | 23-1 v Fortuna SittardFortuna Sittard 1-3 PSV Eindhoven | Dutch Eredivisie |
| 2 | Sat 28 Sep | 22-0 v Willem IIWillem II 0-2 PSV Eindhoven | Dutch Eredivisie |
| 3 | Tue 1 Oct | 21-1 v Sporting CPPSV Eindhoven 1-1 Sporting CP | UEFA Champions League Matchday 2 |
| 4 | Sat 5 Oct | 22-1 v Sparta RotterdamPSV Eindhoven 2-1 Sparta Rotterdam | Dutch Eredivisie |
| 5 | Sat 19 Oct | 22-1 v AZ AlkmaarAZ Alkmaar 1-2 PSV Eindhoven | Dutch Eredivisie |
| 6 | Sat 26 Oct | 26-0 v PEC ZwollePSV Eindhoven 6-0 PEC Zwolle | Dutch Eredivisie |
| 7 | Sat 2 Nov | 2 2-3 v AjaxAjax 3-2 PSV Eindhoven | Dutch Eredivisie |
| 8 | Tue 5 Nov | 2 4-0 v GironaPSV Eindhoven 4-0 Girona | UEFA Champions League Matchday 4 |
| 9 | Sat 9 Nov | 23-0 v NAC BredaNAC Breda 0-3 PSV Eindhoven | Dutch Eredivisie |
| 10 | Sat 23 Nov | 25-0 v FC GroningenPSV Eindhoven 5-0 FC Groningen | Dutch Eredivisie |
| 11 | Wed 27 Nov | 23-2 v Shakhtar DonetskPSV Eindhoven 3-2 Shakhtar Donetsk | UEFA Champions League Matchday 5 |
| 12 | Tue 10 Dec | 20-1 v BrestBrest 1-0 PSV Eindhoven | UEFA Champions League Matchday 6 |
| 13 | Sat 14 Dec | 20-1 v sc Heerenveensc Heerenveen 1-0 PSV Eindhoven | Dutch Eredivisie |
| 14 | Tue 21 Jan | 23-2 v Crvena ZvezdaCrvena Zvezda 2-3 PSV Eindhoven | UEFA Champions League Matchday 7 |
| 15 | Wed 29 Jan | 2 3-2 v LiverpoolPSV Eindhoven 3-2 Liverpool | UEFA Champions League Matchday 8 |
| 16 | Sat 1 Feb | 23-3 v NEC NijmegenNEC Nijmegen 3-3 PSV Eindhoven | Dutch Eredivisie |
| 17 | Sat 8 Feb | 21-1 v Willem IIPSV Eindhoven 1-1 Willem II | Dutch Eredivisie |
| 18 | Tue 4 Mar | 21-7 v ArsenalPSV Eindhoven 1-7 Arsenal | UEFA Champions League Round of 16 |
| 19 | Sat 15 Mar | 23-0 v RKC WaalwijkRKC Waalwijk 0-3 PSV Eindhoven | Dutch Eredivisie |
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