| 1 | Sat 3 Aug 2019 | 1-1 v FC TwenteFC Twente 1-1 PSV Eindhoven | Dutch Eredivisie |
| 2 | Sun 18 Aug 2019 | 2-0 v Heracles AlmeloHeracles Almelo 0-2 PSV Eindhoven | Dutch Eredivisie |
| 3 | Thu 22 Aug 2019 | 3-0 v Apollon LimassolPSV Eindhoven 3-0 Apollon Limassol | Europa League Qualifying Play-off Round |
| 4 | Thu 29 Aug 2019 | 4-0 v Apollon LimassolApollon Limassol 0-4 PSV Eindhoven | Europa League Qualifying Play-off Round |
| 5 | Sun 1 Sep 2019 | 3-1 v RKC WaalwijkRKC Waalwijk 1-3 PSV Eindhoven | Dutch Eredivisie |
| 6 | Sat 14 Sep 2019 | 5-0 v VitessePSV Eindhoven 5-0 Vitesse | Dutch Eredivisie |
| 7 | Thu 19 Sep 2019 | 3-2 v Sporting LisbonPSV Eindhoven 3-2 Sporting Lisbon | Europa League Group D |
| 8 | Sun 22 Sep 2019 | 1-1 v AjaxPSV Eindhoven 1-1 Ajax | Dutch Eredivisie |
| 9 | Sun 29 Sep 2019 | 4-0 v PEC ZwollePEC Zwolle 0-4 PSV Eindhoven | Dutch Eredivisie |
| 10 | Thu 3 Oct 2019 | 4-1 v RosenborgRosenborg 1-4 PSV Eindhoven | Europa League Group D |
| 11 | Sat 19 Oct 2019 | 0-3 v FC UtrechtFC Utrecht 3-0 PSV Eindhoven | Dutch Eredivisie |
| 12 | Thu 24 Oct 2019 | 1-0 v LASK LinzPSV Eindhoven 1-0 LASK Linz | Europa League Group D |
| 13 | Sat 2 Nov 2019 | 2-2 v Sparta RotterdamSparta Rotterdam 2-2 PSV Eindhoven | Dutch Eredivisie |
| 14 | Thu 7 Nov 2019 | 1-4 v LASK LinzLASK Linz 4-1 PSV Eindhoven | Europa League Group D |
| 15 | Sun 10 Nov 2019 | 1-2 v Willem IIWillem II 2-1 PSV Eindhoven | Dutch Eredivisie |
| 16 | Sun 24 Nov 2019 | 2-1 v sc HeerenveenPSV Eindhoven 2-1 sc Heerenveen | Dutch Eredivisie |
| 17 | Thu 28 Nov 2019 | 0-4 v Sporting LisbonSporting Lisbon 4-0 PSV Eindhoven | Europa League Group D |
| 18 | Sun 1 Dec 2019 | 1-1 v FC EmmenFC Emmen 1-1 PSV Eindhoven | Dutch Eredivisie |
| 19 | Sat 7 Dec 2019 | 5-0 v Fortuna SittardPSV Eindhoven 5-0 Fortuna Sittard | Dutch Eredivisie |
| 20 | Thu 12 Dec 2019 | 1-1 v RosenborgPSV Eindhoven 1-1 Rosenborg | Europa League Group D |
| 21 | Sun 15 Dec 2019 | 1-3 v FeyenoordFeyenoord 3-1 PSV Eindhoven | Dutch Eredivisie |
| 22 | Sat 21 Dec 2019 | 4-1 v PEC ZwollePSV Eindhoven 4-1 PEC Zwolle | Dutch Eredivisie |
| 23 | Sun 19 Jan 2020 | 1-1 v VVV VenloVVV Venlo 1-1 PSV Eindhoven | Dutch Eredivisie |
| 24 | Sun 26 Jan 2020 | 1-1 v FC TwentePSV Eindhoven 1-1 FC Twente | Dutch Eredivisie |
| 25 | Sun 2 Feb 2020 | 0-1 v AjaxAjax 1-0 PSV Eindhoven | Dutch Eredivisie |
| 26 | Sat 8 Feb 2020 | 3-0 v Willem IIPSV Eindhoven 3-0 Willem II | Dutch Eredivisie |
| 27 | Sat 15 Feb 2020 | 3-0 v ADO Den HaagADO Den Haag 0-3 PSV Eindhoven | Dutch Eredivisie |
| 28 | Sun 23 Feb 2020 | 2-1 v VitesseVitesse 1-2 PSV Eindhoven | Dutch Eredivisie |
| 29 | Sun 1 Mar 2020 | 1-1 v FeyenoordPSV Eindhoven 1-1 Feyenoord | Dutch Eredivisie |
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