| 1 | Tue 14 Aug 2012 | 13-0 v PortsmouthPlymouth Argyle 3-0 Portsmouth | Capital One Cup First Round |
| 2 | Sat 18 Aug 2012 | 10-2 v Aldershot TownPlymouth Argyle 0-2 Aldershot Town | npower League Two |
| 3 | Tue 21 Aug 2012 | 10-0 v Dagenham & RedbridgeDagenham & Redbridge 0-0 Plymouth Argyle | npower League Two |
| 4 | Sat 25 Aug 2012 | 11-2 v Oxford UnitedOxford United 2-1 Plymouth Argyle | npower League Two |
| 5 | Tue 28 Aug 2012 | 11-1 v BurnleyBurnley 1-1 Plymouth Argyle | Capital One Cup Second Round |
| 6 | Sat 1 Sep 2012 | 13-2 v Northampton TownPlymouth Argyle 3-2 Northampton Town | npower League Two |
| 7 | Sat 8 Sep 2012 | 10-0 v Torquay UnitedTorquay United 0-0 Plymouth Argyle | npower League Two |
| 8 | Sat 15 Sep 2012 | 11-3 v Port ValePlymouth Argyle 1-3 Port Vale | npower League Two |
| 9 | Tue 18 Sep 2012 | 11-1 v Bristol RoversPlymouth Argyle 1-1 Bristol Rovers | npower League Two |
| 10 | Sat 22 Sep 2012 | 13-2 v MorecambeMorecambe 2-3 Plymouth Argyle | npower League Two |
| 11 | Sat 29 Sep 2012 | 11-1 v Southend UnitedPlymouth Argyle 1-1 Southend United | npower League Two |
| 12 | Tue 2 Oct 2012 | 11-1 v Wycombe WanderersWycombe Wanderers 1-1 Plymouth Argyle | npower League Two |
| 13 | Sat 6 Oct 2012 | 11-2 v AFC WimbledonPlymouth Argyle 1-2 AFC Wimbledon | npower League Two |
| 14 | Sat 20 Oct 2012 | 13-1 v RochdalePlymouth Argyle 3-1 Rochdale | npower League Two |
| 15 | Tue 23 Oct 2012 | 11-2 v Cheltenham TownCheltenham Town 2-1 Plymouth Argyle | npower League Two |
| 16 | Sat 27 Oct 2012 | 10-1 v Rotherham UnitedRotherham United 1-0 Plymouth Argyle | npower League Two |
| 17 | Wed 7 Nov 2012 | 11-2 v Burton AlbionPlymouth Argyle 1-2 Burton Albion | npower League Two |
| 18 | Sat 26 Jan 2013 | 10-0 v Accrington StanleyPlymouth Argyle 0-0 Accrington Stanley | npower League Two |
| 19 | Sat 2 Feb 2013 | 10-0 v Dagenham & RedbridgePlymouth Argyle 0-0 Dagenham & Redbridge | npower League Two |
| 20 | Sat 9 Feb 2013 | 12-1 v Aldershot TownAldershot Town 1-2 Plymouth Argyle | npower League Two |
| 21 | Sat 16 Feb 2013 | 10-1 v Oxford UnitedPlymouth Argyle 0-1 Oxford United | npower League Two |
| 22 | Sat 23 Feb 2013 | 10-1 v Northampton TownNorthampton Town 1-0 Plymouth Argyle | npower League Two |
| 23 | Tue 26 Feb 2013 | 11-1 v AFC WimbledonAFC Wimbledon 1-1 Plymouth Argyle | npower League Two |
| 24 | Sat 2 Mar 2013 | 12-1 v BarnetPlymouth Argyle 2-1 Barnet | npower League Two |
| 25 | Sat 9 Mar 2013 | 11-2 v GillinghamGillingham 2-1 Plymouth Argyle | npower League Two |
| 26 | Tue 12 Mar 2013 | 10-0 v Bradford CityPlymouth Argyle 0-0 Bradford City | npower League Two |
| 27 | Sat 16 Mar 2013 | 12-1 v Fleetwood TownPlymouth Argyle 2-1 Fleetwood Town | npower League Two |
| 28 | Tue 19 Mar 2013 | 12-0 v Southend UnitedSouthend United 0-2 Plymouth Argyle | npower League Two |
| 29 | Sat 30 Mar 2013 | 11-0 v Exeter CityPlymouth Argyle 1-0 Exeter City | npower League Two |
| 30 | Mon 1 Apr 2013 | 10-2 v York CityYork City 2-0 Plymouth Argyle | npower League Two |
| 31 | Sat 6 Apr 2013 | 12-0 v Cheltenham TownPlymouth Argyle 2-0 Cheltenham Town | npower League Two |
| 32 | Sat 13 Apr 2013 | 10-1 v Burton AlbionBurton Albion 1-0 Plymouth Argyle | npower League Two |
| 33 | Tue 16 Apr 2013 | 12-1 v ChesterfieldChesterfield 1-2 Plymouth Argyle | npower League Two |
| 34 | Sat 20 Apr 2013 | 10-1 v Rotherham UnitedPlymouth Argyle 0-1 Rotherham United | npower League Two |
| 35 | Sat 27 Apr 2013 | 10-1 v RochdaleRochdale 1-0 Plymouth Argyle | npower League Two |
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