| 1 | Sun 24 Aug | 150-1 v 1 FC KölnMainz 05 0-1 1 FC Köln | German Bundesliga |
| 2 | Thu 28 Aug | 154-1 v RosenborgMainz 05 4-1 Rosenborg | UEFA Europa Conference League |
| 3 | Sat 27 Sep | 150-2 v Borussia DortmundMainz 05 0-2 Borussia Dortmund | German Bundesliga |
| 4 | Thu 2 Oct | 151-0 v Omonia NicosiaOmonia Nicosia 0-1 Mainz 05 | UEFA Europa Conference League Matchday 1 |
| 5 | Sun 5 Oct | 150-4 v Hamburger SVHamburger SV 4-0 Mainz 05 | German Bundesliga |
| 6 | Thu 23 Oct | 151-0 v Zrinjski MostarMainz 05 1-0 Zrinjski Mostar | UEFA Europa Conference League Matchday 2 |
| 7 | Sat 1 Nov | 151-1 v Werder BremenMainz 05 1-1 Werder Bremen | German Bundesliga |
| 8 | Thu 6 Nov | 15 2-1 v FiorentinaMainz 05 2-1 Fiorentina | UEFA Europa Conference League Matchday 3 |
| 9 | Sun 9 Nov | 150-1 v Eintracht FrankfurtEintracht Frankfurt 1-0 Mainz 05 | German Bundesliga |
| 10 | Fri 21 Nov | 151-1 v TSG HoffenheimMainz 05 1-1 TSG Hoffenheim | German Bundesliga |
| 11 | Thu 27 Nov | 150-1 v CS Universitatea CraiovaCS Universitatea Craiova 1-0 Mainz 05 | UEFA Europa Conference League Matchday 4 |
| 12 | Sun 30 Nov | 150-4 v SC FreiburgSC Freiburg 4-0 Mainz 05 | German Bundesliga |
| 13 | Sun 14 Dec | 152-2 v Bayern MunichBayern Munich 2-2 Mainz 05 | German Bundesliga |
| 14 | Thu 18 Dec | 152-0 v SamsunsporMainz 05 2-0 Samsunspor | UEFA Europa Conference League Matchday 6 |
| 15 | Sat 10 Jan | 152-2 v Union BerlinUnion Berlin 2-2 Mainz 05 | German Bundesliga |
| 16 | Tue 13 Jan | 152-1 v 1 FC HeidenheimMainz 05 2-1 1 FC Heidenheim | German Bundesliga |
| 17 | Sat 17 Jan | 151-2 v 1 FC Köln1 FC Köln 2-1 Mainz 05 | German Bundesliga |
| 18 | Sat 24 Jan | 153-1 v VfL WolfsburgMainz 05 3-1 VfL Wolfsburg | German Bundesliga |
| 19 | Sat 31 Jan | 152-1 v RB LeipzigRB Leipzig 1-2 Mainz 05 | German Bundesliga |
| 20 | Sat 7 Feb | 152-0 v FC AugsburgMainz 05 2-0 FC Augsburg | German Bundesliga |
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