| 1 | Sun 31 Aug | 110-3 v Borussia DortmundBorussia Dortmund 3-0 Union Berlin |
| 2 | Sat 13 Sep | 112-4 v TSG HoffenheimUnion Berlin 2-4 TSG Hoffenheim |
| 3 | Sun 21 Sep | 114-3 v Eintracht FrankfurtEintracht Frankfurt 3-4 Union Berlin |
| 4 | Sun 28 Sep | 110-0 v Hamburger SVUnion Berlin 0-0 Hamburger SV |
| 5 | Sat 4 Oct | 110-2 v Bayer LeverkusenBayer Leverkusen 2-0 Union Berlin |
| 6 | Fri 17 Oct | 113-1 v Borussia MönchengladbachUnion Berlin 3-1 Borussia Mönchengladbach |
| 7 | Fri 24 Oct | 110-1 v Werder BremenWerder Bremen 1-0 Union Berlin |
| 8 | Sat 8 Nov | 112-2 v Bayern MunichUnion Berlin 2-2 Bayern Munich |
| 9 | Sun 23 Nov | 111-0 v FC St PauliFC St Pauli 0-1 Union Berlin |
| 10 | Sat 29 Nov | 111-2 v 1 FC HeidenheimUnion Berlin 1-2 1 FC Heidenheim |
| 11 | Sat 6 Dec | 111-3 v VfL WolfsburgVfL Wolfsburg 3-1 Union Berlin |
| 12 | Fri 12 Dec | 113-1 v RB LeipzigUnion Berlin 3-1 RB Leipzig |
| 13 | Sat 20 Dec | 111-0 v 1 FC Köln1 FC Köln 0-1 Union Berlin |
| 14 | Sat 10 Jan | 112-2 v Mainz 05Union Berlin 2-2 Mainz 05 |
| 15 | Thu 15 Jan | 111-1 v FC AugsburgFC Augsburg 1-1 Union Berlin |
| 16 | Sun 18 Jan | 111-1 v VfB StuttgartVfB Stuttgart 1-1 Union Berlin |
| 17 | Sat 24 Jan | 110-3 v Borussia DortmundUnion Berlin 0-3 Borussia Dortmund |
| 18 | Sat 31 Jan | 111-3 v TSG HoffenheimTSG Hoffenheim 3-1 Union Berlin |
| 19 | Fri 6 Feb | 111-1 v Eintracht FrankfurtUnion Berlin 1-1 Eintracht Frankfurt |
| 20 | Sat 14 Feb | 112-3 v Hamburger SVHamburger SV 3-2 Union Berlin |
| 21 | Sat 21 Feb | 111-0 v Bayer LeverkusenUnion Berlin 1-0 Bayer Leverkusen |
| 22 | Sat 28 Feb | 110-1 v Borussia MönchengladbachBorussia Mönchengladbach 1-0 Union Berlin |
| 23 | Sun 8 Mar | 111-4 v Werder BremenUnion Berlin 1-4 Werder Bremen |
| 24 | Sun 15 Mar | 111-0 v SC FreiburgSC Freiburg 0-1 Union Berlin |
| 25 | Sat 21 Mar | 110-4 v Bayern MunichBayern Munich 4-0 Union Berlin |
| 26 | Sun 5 Apr | 111-1 v FC St PauliUnion Berlin 1-1 FC St Pauli |
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