| 1 | Sun 31 Aug | 210-3 v Borussia DortmundBorussia Dortmund 3-0 Union Berlin |
| 2 | Sat 13 Sep | 212-4 v TSG HoffenheimUnion Berlin 2-4 TSG Hoffenheim |
| 3 | Sun 21 Sep | 214-3 v Eintracht FrankfurtEintracht Frankfurt 3-4 Union Berlin |
| 4 | Sun 28 Sep | 210-0 v Hamburger SVUnion Berlin 0-0 Hamburger SV |
| 5 | Sat 4 Oct | 210-2 v Bayer LeverkusenBayer Leverkusen 2-0 Union Berlin |
| 6 | Fri 17 Oct | 213-1 v Borussia MönchengladbachUnion Berlin 3-1 Borussia Mönchengladbach |
| 7 | Fri 24 Oct | 210-1 v Werder BremenWerder Bremen 1-0 Union Berlin |
| 8 | Sat 1 Nov | 210-0 v SC FreiburgUnion Berlin 0-0 SC Freiburg |
| 9 | Sat 8 Nov | 212-2 v Bayern MunichUnion Berlin 2-2 Bayern Munich |
| 10 | Sun 23 Nov | 211-0 v FC St PauliFC St Pauli 0-1 Union Berlin |
| 11 | Fri 12 Dec | 213-1 v RB LeipzigUnion Berlin 3-1 RB Leipzig |
| 12 | Sat 20 Dec | 211-0 v 1 FC Köln1 FC Köln 0-1 Union Berlin |
| 13 | Sat 14 Feb | 212-3 v Hamburger SVHamburger SV 3-2 Union Berlin |
| 14 | Sat 21 Feb | 211-0 v Bayer LeverkusenUnion Berlin 1-0 Bayer Leverkusen |
| 15 | Sun 8 Mar | 211-4 v Werder BremenUnion Berlin 1-4 Werder Bremen |
| 16 | Sun 15 Mar | 211-0 v SC FreiburgSC Freiburg 0-1 Union Berlin |
| 17 | Sat 21 Mar | 210-4 v Bayern MunichBayern Munich 4-0 Union Berlin |
| 18 | Sat 11 Apr | 211-3 v 1 FC Heidenheim1 FC Heidenheim 3-1 Union Berlin |
| 19 | Sat 18 Apr | 211-2 v VfL WolfsburgUnion Berlin 1-2 VfL Wolfsburg |
| 20 | Sat 2 May | 212-2 v 1 FC KölnUnion Berlin 2-2 1 FC Köln |
| 21 | Sun 10 May | 213-1 v Mainz 05Mainz 05 1-3 Union Berlin |
| 22 | Sat 16 May | 214-0 v FC AugsburgUnion Berlin 4-0 FC Augsburg |
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