| 1 | Tue 14 Aug 2012 | 31-2 v Tranmere RoversChesterfield 1-2 Tranmere Rovers | Capital One Cup First Round |
| 2 | Sat 18 Aug 2012 | 30-1 v AFC WimbledonAFC Wimbledon 1-0 Chesterfield | npower League Two |
| 3 | Tue 21 Aug 2012 | 31-1 v RochdaleChesterfield 1-1 Rochdale | npower League Two |
| 4 | Sat 25 Aug 2012 | 31-1 v Rotherham UnitedChesterfield 1-1 Rotherham United | npower League Two |
| 5 | Sat 20 Oct 2012 | 31-0 v Exeter CityExeter City 0-1 Chesterfield | npower League Two |
| 6 | Tue 23 Oct 2012 | 31-2 v Fleetwood TownChesterfield 1-2 Fleetwood Town | npower League Two |
| 7 | Sat 27 Oct 2012 | 30-1 v BarnetChesterfield 0-1 Barnet | npower League Two |
| 8 | Sat 3 Nov 2012 | 36-1 v Hartlepool UnitedChesterfield 6-1 Hartlepool United | FA Cup with Budweiser First Round |
| 9 | Tue 6 Nov 2012 | 30-0 v Bradford CityBradford City 0-0 Chesterfield | npower League Two |
| 10 | Sat 10 Nov 2012 | 32-3 v Bristol RoversBristol Rovers 3-2 Chesterfield | npower League Two |
| 11 | Sat 17 Nov 2012 | 32-1 v Oxford UnitedChesterfield 2-1 Oxford United | npower League Two |
| 12 | Tue 20 Nov 2012 | 34-1 v Cheltenham TownChesterfield 4-1 Cheltenham Town | npower League Two |
| 13 | Sat 24 Nov 2012 | 31-0 v Plymouth ArgylePlymouth Argyle 0-1 Chesterfield | npower League Two |
| 14 | Sat 1 Dec 2012 | 31-2 v Tranmere RoversTranmere Rovers 2-1 Chesterfield | FA Cup with Budweiser Second Round |
| 15 | Sat 8 Dec 2012 | 32-0 v Port ValePort Vale 0-2 Chesterfield | npower League Two |
| 16 | Sat 15 Dec 2012 | 31-1 v Burton AlbionChesterfield 1-1 Burton Albion | npower League Two |
| 17 | Fri 21 Dec 2012 | 30-3 v Southend UnitedSouthend United 3-0 Chesterfield | npower League Two |
| 18 | Wed 26 Dec 2012 | 33-0 v York CityChesterfield 3-0 York City | npower League Two |
| 19 | Sat 29 Dec 2012 | 31-1 v MorecambeChesterfield 1-1 Morecambe | npower League Two |
| 20 | Tue 1 Jan 2013 | 30-1 v Accrington StanleyAccrington Stanley 1-0 Chesterfield | npower League Two |
| 21 | Sat 5 Jan 2013 | 31-2 v Wycombe WanderersWycombe Wanderers 2-1 Chesterfield | npower League Two |
| 22 | Sat 12 Jan 2013 | 33-0 v Northampton TownChesterfield 3-0 Northampton Town | npower League Two |
| 23 | Sat 26 Jan 2013 | 30-1 v Southend UnitedChesterfield 0-1 Southend United | npower League Two |
| 24 | Sat 2 Feb 2013 | 31-1 v RochdaleRochdale 1-1 Chesterfield | npower League Two |
| 25 | Sat 9 Feb 2013 | 32-0 v AFC WimbledonChesterfield 2-0 AFC Wimbledon | npower League Two |
| 26 | Sat 16 Feb 2013 | 30-1 v Rotherham UnitedRotherham United 1-0 Chesterfield | npower League Two |
| 27 | Sat 23 Feb 2013 | 30-1 v GillinghamChesterfield 0-1 Gillingham | npower League Two |
| 28 | Tue 26 Feb 2013 | 30-0 v Aldershot TownChesterfield 0-0 Aldershot Town | npower League Two |
| 29 | Sat 2 Mar 2013 | 31-0 v Dagenham & RedbridgeDagenham & Redbridge 0-1 Chesterfield | npower League Two |
| 30 | Tue 5 Mar 2013 | 30-1 v Cheltenham TownCheltenham Town 1-0 Chesterfield | npower League Two |
| 31 | Sat 9 Mar 2013 | 32-0 v Bristol RoversChesterfield 2-0 Bristol Rovers | npower League Two |
| 32 | Sat 16 Mar 2013 | 31-0 v Oxford UnitedOxford United 0-1 Chesterfield | npower League Two |
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