| 1 | Sat 3 Aug 2013 | 2-0 v PeterheadPeterhead 0-2 Alloa Athletic | Scottish Communities Cup First Round |
| 2 | Sat 10 Aug 2013 | 21-0 v LivingstonAlloa Athletic 1-0 Livingston | Scottish Championship |
| 3 | Sat 17 Aug 2013 | 20-1 v DundeeDundee 1-0 Alloa Athletic | Scottish Championship |
| 4 | Sat 24 Aug 2013 | 23-1 v CowdenbeathAlloa Athletic 3-1 Cowdenbeath | Scottish Championship |
| 5 | Tue 27 Aug 2013 | 20-0 v AberdeenAberdeen 0-0 Alloa Athletic | Scottish Communities Cup Second Round |
| 6 | Sat 31 Aug 2013 | 20-0 v Queen of the SouthQueen of the South 0-0 Alloa Athletic | Scottish Championship |
| 7 | Sat 14 Sep 2013 | 21-2 v DumbartonAlloa Athletic 1-2 Dumbarton | Scottish Championship |
| 8 | Sat 21 Sep 2013 | 22-4 v Raith RoversRaith Rovers 4-2 Alloa Athletic | Scottish Championship |
| 9 | Sat 28 Sep 2013 | 21-0 v Hamilton AcademicalAlloa Athletic 1-0 Hamilton Academical | Scottish Championship |
| 10 | Sat 5 Oct 2013 | 22-0 v MortonMorton 0-2 Alloa Athletic | Scottish Championship |
| 11 | Sat 12 Oct 2013 | 20-0 v FalkirkAlloa Athletic 0-0 Falkirk | Scottish Championship |
| 12 | Sat 19 Oct 2013 | 22-3 v LivingstonLivingston 3-2 Alloa Athletic | Scottish Championship |
| 13 | Sat 26 Oct 2013 | 20-3 v Queen of the SouthAlloa Athletic 0-3 Queen of the South | Scottish Championship |
| 14 | Sat 9 Nov 2013 | 22-0 v CowdenbeathCowdenbeath 0-2 Alloa Athletic | Scottish Championship |
| 15 | Sat 16 Nov 2013 | 21-0 v Raith RoversAlloa Athletic 1-0 Raith Rovers | Scottish Championship |
| 16 | Sat 30 Nov 2013 | 23-2 v Stirling AlbionAlloa Athletic 3-2 Stirling Albion | Scottish FA Cup Fourth Round |
| 17 | Sat 7 Dec 2013 | 21-0 v Hamilton AcademicalHamilton Academical 0-1 Alloa Athletic | Scottish Championship |
| 18 | Sat 14 Dec 2013 | 22-0 v MortonAlloa Athletic 2-0 Morton | Scottish Championship |
| 19 | Sat 21 Dec 2013 | 20-1 v DundeeAlloa Athletic 0-1 Dundee | Scottish Championship |
| 20 | Sat 28 Dec 2013 | 40-0 v FalkirkFalkirk 0-0 Alloa Athletic | Scottish Championship |
| 21 | Thu 2 Jan 2014 | 20-1 v CowdenbeathAlloa Athletic 0-1 Cowdenbeath | Scottish Championship |
| 22 | Sat 11 Jan 2014 | 21-3 v Queen of the SouthQueen of the South 3-1 Alloa Athletic | Scottish Championship |
| 23 | Sat 18 Jan 2014 | 21-5 v DumbartonAlloa Athletic 1-5 Dumbarton | Scottish Championship |
| 24 | Sat 1 Feb 2014 | 21-1 v DundeeDundee 1-1 Alloa Athletic | Scottish Championship |
| 25 | Sat 8 Feb 2014 | 20-1 v DumbartonAlloa Athletic 0-1 Dumbarton | Scottish FA Cup Fifth Round |
| 26 | Sat 15 Feb 2014 | 20-3 v LivingstonAlloa Athletic 0-3 Livingston | Scottish Championship |
| 27 | Sat 22 Feb 2014 | 21-0 v MortonMorton 0-1 Alloa Athletic | Scottish Championship |
| 28 | Tue 25 Feb 2014 | 21-1 v Raith RoversRaith Rovers 1-1 Alloa Athletic | Scottish Championship |
| 29 | Sat 1 Mar 2014 | 20-3 v Hamilton AcademicalAlloa Athletic 0-3 Hamilton Academical | Scottish Championship |
| 30 | Sat 8 Mar 2014 | 22-2 v CowdenbeathCowdenbeath 2-2 Alloa Athletic | Scottish Championship |
| 31 | Sat 15 Mar 2014 | 20-1 v Queen of the SouthAlloa Athletic 0-1 Queen of the South | Scottish Championship |
| 32 | Sat 22 Mar 2014 | 23-0 v FalkirkAlloa Athletic 3-0 Falkirk | Scottish Championship |
| 33 | Tue 25 Mar 2014 | 20-2 v LivingstonLivingston 2-0 Alloa Athletic | Scottish Championship |
| 34 | Sat 29 Mar 2014 | 20-1 v Raith RoversAlloa Athletic 0-1 Raith Rovers | Scottish Championship |
| 35 | Sat 5 Apr 2014 | 21-4 v DumbartonDumbarton 4-1 Alloa Athletic | Scottish Championship |
| 36 | Sat 12 Apr 2014 | 22-0 v MortonAlloa Athletic 2-0 Morton | Scottish Championship |
| 37 | Sat 19 Apr 2014 | 21-2 v Hamilton AcademicalHamilton Academical 2-1 Alloa Athletic | Scottish Championship |
| 38 | Sat 26 Apr 2014 | 20-3 v DundeeAlloa Athletic 0-3 Dundee | Scottish Championship |
| 39 | Sat 3 May 2014 | 21-3 v FalkirkFalkirk 3-1 Alloa Athletic | Scottish Championship |
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