| 1 | Sat 18 Sep 2021 | 240-2 v OsasunaAlavés 0-2 Osasuna | Spanish La Liga |
| 2 | Wed 22 Sep 2021 | 240-1 v EspanyolEspanyol 1-0 Alavés | Spanish La Liga |
| 3 | Sat 25 Sep 2021 | 241-0 v Atlético MadridAlavés 1-0 Atlético Madrid | Spanish La Liga |
| 4 | Fri 1 Oct 2021 | 240-1 v Athletic BilbaoAthletic Bilbao 1-0 Alavés | Spanish La Liga |
| 5 | Mon 18 Oct 2021 | 240-1 v Real BetisAlavés 0-1 Real Betis | Spanish La Liga |
| 6 | Sat 23 Oct 2021 | 242-0 v CádizCádiz 0-2 Alavés | Spanish La Liga |
| 7 | Sat 20 Nov 2021 | 242-2 v SevillaSevilla 2-2 Alavés | Spanish La Liga |
| 8 | Sat 18 Dec 2021 | 240-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 9 | Tue 21 Dec 2021 | 242-5 v VillarrealVillarreal 5-2 Alavés | Spanish La Liga |
| 10 | Sun 2 Jan 2022 | 241-1 v Real SociedadAlavés 1-1 Real Sociedad | Spanish La Liga |
| 11 | Sun 9 Jan 2022 | 240-0 v Athletic BilbaoAlavés 0-0 Athletic Bilbao | Spanish La Liga |
| 12 | Tue 18 Jan 2022 | 240-4 v Real BetisReal Betis 4-0 Alavés | Spanish La Liga |
| 13 | Sun 23 Jan 2022 | 240-1 v BarcelonaAlavés 0-1 Barcelona | Spanish La Liga |
| 14 | Sat 5 Feb 2022 | 241-3 v ElcheElche 3-1 Alavés | Spanish La Liga |
| 15 | Sun 13 Mar 2022 | 240-1 v Real SociedadReal Sociedad 1-0 Alavés | Spanish La Liga |
| 16 | Sat 19 Mar 2022 | 24 2-3 v GranadaAlavés 2-3 Granada | Spanish La Liga |
| 17 | Sat 2 Apr 2022 | 241-4 v Atlético MadridAtlético Madrid 4-1 Alavés | Spanish La Liga |
| 18 | Sat 16 Apr 2022 | 241-0 v Rayo VallecanoAlavés 1-0 Rayo Vallecano | Spanish La Liga |
| 19 | Tue 19 Apr 2022 | 241-2 v MallorcaMallorca 2-1 Alavés | Spanish La Liga |
| 20 | Wed 11 May 2022 | 242-1 v EspanyolAlavés 2-1 Espanyol | Spanish La Liga |
| 21 | Sun 15 May 2022 | 24 1-3 v LevanteLevante 3-1 Alavés | Spanish La Liga |
| 22 | Sun 22 May 2022 | 240-1 v CádizAlavés 0-1 Cádiz | Spanish La Liga |
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