| 1 | Sat 14 Aug 2021 | 181-4 v Real MadridAlavés 1-4 Real Madrid | Spanish La Liga |
| 2 | Sat 21 Aug 2021 | 180-1 v MallorcaAlavés 0-1 Mallorca | Spanish La Liga |
| 3 | Fri 27 Aug 2021 | 180-3 v ValenciaValencia 3-0 Alavés | Spanish La Liga |
| 4 | Sat 18 Sep 2021 | 180-2 v OsasunaAlavés 0-2 Osasuna | Spanish La Liga |
| 5 | Wed 22 Sep 2021 | 180-1 v EspanyolEspanyol 1-0 Alavés | Spanish La Liga |
| 6 | Sat 25 Sep 2021 | 181-0 v Atlético MadridAlavés 1-0 Atlético Madrid | Spanish La Liga |
| 7 | Fri 1 Oct 2021 | 180-1 v Athletic BilbaoAthletic Bilbao 1-0 Alavés | Spanish La Liga |
| 8 | Mon 18 Oct 2021 | 180-1 v Real BetisAlavés 0-1 Real Betis | Spanish La Liga |
| 9 | Sat 23 Oct 2021 | 182-0 v CádizCádiz 0-2 Alavés | Spanish La Liga |
| 10 | Tue 26 Oct 2021 | 181-0 v ElcheAlavés 1-0 Elche | Spanish La Liga |
| 11 | Sat 30 Oct 2021 | 181-1 v BarcelonaBarcelona 1-1 Alavés | Spanish La Liga |
| 12 | Sat 6 Nov 2021 | 182-1 v LevanteAlavés 2-1 Levante | Spanish La Liga |
| 13 | Sat 27 Nov 2021 | 181-2 v Celta VigoAlavés 1-2 Celta Vigo | Spanish La Liga |
| 14 | Fri 3 Dec 2021 | 181-2 v GranadaGranada 2-1 Alavés | Spanish La Liga |
| 15 | Sat 11 Dec 2021 | 181-1 v GetafeAlavés 1-1 Getafe | Spanish La Liga |
| 16 | Sat 18 Dec 2021 | 180-2 v Rayo VallecanoRayo Vallecano 2-0 Alavés | Spanish La Liga |
| 17 | Sun 9 Jan 2022 | 180-0 v Athletic BilbaoAlavés 0-0 Athletic Bilbao | Spanish La Liga |
| 18 | Sat 26 Feb 2022 | 182-2 v GetafeGetafe 2-2 Alavés | Spanish La Liga |
| 19 | Sat 2 Apr 2022 | 181-4 v Atlético MadridAtlético Madrid 4-1 Alavés | Spanish La Liga |
| 20 | Sun 10 Apr 2022 | 180-1 v OsasunaOsasuna 1-0 Alavés | Spanish La Liga |
| 21 | Tue 19 Apr 2022 | 181-2 v MallorcaMallorca 2-1 Alavés | Spanish La Liga |
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