| 1 | Sun 20 Sep 2020 | 16 1-2 v GranadaGranada 2-1 Alavés | Spanish La Liga |
| 2 | Sat 26 Sep 2020 | 160-0 v GetafeAlavés 0-0 Getafe | Spanish La Liga |
| 3 | Wed 30 Sep 2020 | 161-3 v VillarrealVillarreal 3-1 Alavés | Spanish La Liga |
| 4 | Sun 4 Oct 2020 | 161-0 v Athletic BilbaoAlavés 1-0 Athletic Bilbao | Spanish La Liga |
| 5 | Sun 18 Oct 2020 | 160-2 v ElcheAlavés 0-2 Elche | Spanish La Liga |
| 6 | Sun 25 Oct 2020 | 162-0 v Real ValladolidReal Valladolid 0-2 Alavés | Spanish La Liga |
| 7 | Sat 31 Oct 2020 | 161-1 v BarcelonaAlavés 1-1 Barcelona | Spanish La Liga |
| 8 | Sun 8 Nov 2020 | 16 1-1 v LevanteLevante 1-1 Alavés | Spanish La Liga |
| 9 | Sat 28 Nov 2020 | 16 2-1 v Real MadridReal Madrid 1-2 Alavés | Spanish La Liga |
| 10 | Sun 6 Dec 2020 | 160-0 v Real SociedadAlavés 0-0 Real Sociedad | Spanish La Liga |
| 11 | Sat 12 Dec 2020 | 160-1 v HuescaHuesca 1-0 Alavés | Spanish La Liga |
| 12 | Wed 23 Dec 2020 | 16 2-1 v EibarAlavés 2-1 Eibar | Spanish La Liga |
| 13 | Thu 31 Dec 2020 | 161-1 v OsasunaOsasuna 1-1 Alavés | Spanish La Liga |
| 14 | Sun 3 Jan 2021 | 161-2 v Atlético MadridAlavés 1-2 Atlético Madrid | Spanish La Liga |
| 15 | Sun 10 Jan 2021 | 161-3 v CádizCádiz 3-1 Alavés | Spanish La Liga |
| 16 | Tue 19 Jan 2021 | 16 1-2 v SevillaAlavés 1-2 Sevilla | Spanish La Liga |
| 17 | Sat 23 Jan 2021 | 16 1-4 v Real MadridAlavés 1-4 Real Madrid | Spanish La Liga |
| 18 | Fri 5 Feb 2021 | 16 1-0 v Real ValladolidAlavés 1-0 Real Valladolid | Spanish La Liga |
| 19 | Sat 13 Feb 2021 | 161-5 v BarcelonaBarcelona 5-1 Alavés | Spanish La Liga |
| 20 | Sun 21 Feb 2021 | 160-4 v Real SociedadReal Sociedad 4-0 Alavés | Spanish La Liga |
| 21 | Sat 27 Feb 2021 | 160-1 v OsasunaAlavés 0-1 Osasuna | Spanish La Liga |
| 22 | Mon 8 Mar 2021 | 16 2-3 v Real BetisReal Betis 3-2 Alavés | Spanish La Liga |
| 23 | Sat 13 Mar 2021 | 161-1 v CádizAlavés 1-1 Cádiz | Spanish La Liga |
| 24 | Sun 21 Mar 2021 | 160-1 v Atlético MadridAtlético Madrid 1-0 Alavés | Spanish La Liga |
| 25 | Sun 4 Apr 2021 | 16 1-3 v Celta VigoAlavés 1-3 Celta Vigo | Spanish La Liga |
| 26 | Sat 10 Apr 2021 | 160-0 v Athletic BilbaoAthletic Bilbao 0-0 Alavés | Spanish La Liga |
| 27 | Wed 21 Apr 2021 | 16 2-1 v VillarrealAlavés 2-1 Villarreal | Spanish La Liga |
| 28 | Sat 24 Apr 2021 | 161-1 v ValenciaValencia 1-1 Alavés | Spanish La Liga |
| 29 | Sat 1 May 2021 | 160-3 v EibarEibar 3-0 Alavés | Spanish La Liga |
| 30 | Sat 8 May 2021 | 162-2 v LevanteAlavés 2-2 Levante | Spanish La Liga |
| 31 | Tue 11 May 2021 | 16 2-0 v ElcheElche 0-2 Alavés | Spanish La Liga |
| 32 | Sun 23 May 2021 | 160-1 v SevillaSevilla 1-0 Alavés | Spanish La Liga |
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