| 1 | Sat 14 Aug 2021 | 101-1 v Bayer 04 Leverkusen1. FC Union Berlin 1-1 Bayer 04 Leverkusen | German Bundesliga |
| 2 | Sun 22 Aug 2021 | 102-2 v 1899 Hoffenheim1899 Hoffenheim 2-2 1. FC Union Berlin | German Bundesliga |
| 3 | Sun 29 Aug 2021 | 102-1 v Borussia Mönchengladbach1. FC Union Berlin 2-1 Borussia Mönchengladbach | German Bundesliga |
| 4 | Sat 11 Sep 2021 | 100-0 v FC Augsburg1. FC Union Berlin 0-0 FC Augsburg | German Bundesliga |
| 5 | Thu 16 Sep 2021 | 101-3 v Slavia PragueSlavia Prague 3-1 1. FC Union Berlin | UEFA Europa Conference League |
| 6 | Sun 19 Sep 2021 | 102-4 v Borussia DortmundBorussia Dortmund 4-2 1. FC Union Berlin | German Bundesliga |
| 7 | Sat 25 Sep 2021 | 101-0 v Arminia Bielefeld1. FC Union Berlin 1-0 Arminia Bielefeld | German Bundesliga |
| 8 | Sun 3 Oct 2021 | 10 2-1 v Mainz 05Mainz 05 1-2 1. FC Union Berlin | German Bundesliga |
| 9 | Sat 16 Oct 2021 | 102-0 v VfL Wolfsburg1. FC Union Berlin 2-0 VfL Wolfsburg | German Bundesliga |
| 10 | Thu 21 Oct 2021 | 101-3 v FeyenoordFeyenoord 3-1 1. FC Union Berlin | UEFA Europa Conference League |
| 11 | Sat 20 Nov 2021 | 102-0 v Hertha Berlin1. FC Union Berlin 2-0 Hertha Berlin | German Bundesliga |
| 12 | Thu 25 Nov 2021 | 101-0 v Maccabi HaifaMaccabi Haifa 0-1 1. FC Union Berlin | UEFA Europa Conference League |
| 13 | Sun 28 Nov 2021 | 101-2 v Eintracht FrankfurtEintracht Frankfurt 2-1 1. FC Union Berlin | German Bundesliga |
| 14 | Fri 3 Dec 2021 | 102-1 v RB Leipzig1. FC Union Berlin 2-1 RB Leipzig | German Bundesliga |
| 15 | Thu 9 Dec 2021 | 101-1 v Slavia Prague1. FC Union Berlin 1-1 Slavia Prague | UEFA Europa Conference League |
| 16 | Sun 12 Dec 2021 | 100-1 v Greuther FürthGreuther Fürth 1-0 1. FC Union Berlin | German Bundesliga |
| 17 | Sat 18 Dec 2021 | 101-0 v VfL BochumVfL Bochum 0-1 1. FC Union Berlin | German Bundesliga |
| 18 | Sat 8 Jan 2022 | 102-2 v Bayer 04 LeverkusenBayer 04 Leverkusen 2-2 1. FC Union Berlin | German Bundesliga |
| 19 | Sat 15 Jan 2022 | 102-1 v 1899 Hoffenheim1. FC Union Berlin 2-1 1899 Hoffenheim | German Bundesliga |
| 20 | Sat 22 Jan 2022 | 102-1 v Borussia MönchengladbachBorussia Mönchengladbach 1-2 1. FC Union Berlin | German Bundesliga |
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